Stereoselective Synthesis of Alkenyl Silanes, Sulfones, Phosphine Oxides, and Nitroolefins by Radical C–S Bond Cleavage of Arylalkenyl Sulfides

Stereoselective Synthesis of Alkenyl Silanes, Sulfones, Phosphine Oxides, and Nitroolefins by Radical C–S Bond Cleavage of Arylalkenyl Sulfides

A radical-mediated approach has been introduced for the C–S bond activation of arylalkenyl sulfides. The protocol provides an efficient approach for the generation of various alkenes including alkenyl silanes, sulfones, phosphine oxides, and nitroolefins. In most cases, these radical substitutions a...

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Veröffentlicht in:Organic letters 2017-03, Vol.19 (5), p.1100-1103
Hauptverfasser: Lin, Ya-mei, Lu, Guo-ping, Wang, Rong-kang, Yi, Wen-bin
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creator Lin, Ya-mei
Lu, Guo-ping
Wang, Rong-kang
Yi, Wen-bin
description A radical-mediated approach has been introduced for the C–S bond activation of arylalkenyl sulfides. The protocol provides an efficient approach for the generation of various alkenes including alkenyl silanes, sulfones, phosphine oxides, and nitroolefins. In most cases, these radical substitutions are performed under metal-free conditions with stereospecificity.
doi_str_mv 10.1021/acs.orglett.7b00126
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title Stereoselective Synthesis of Alkenyl Silanes, Sulfones, Phosphine Oxides, and Nitroolefins by Radical C–S Bond Cleavage of Arylalkenyl Sulfides
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