Enhancement of C−H Oxidizing Ability in Co–O2 Complexes through an Isolated Heterobimetallic Oxo Intermediate

The characterization of intermediates formed through the reaction of transition‐metal complexes with dioxygen (O2) is important for understanding oxidation in biological and synthetic processes. Here, the reaction of the diketiminate‐supported cobalt(I) complex LtBuCo with O2 gives a rare example of...

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Veröffentlicht in:	Angewandte Chemie International Edition 2017-03, Vol.56 (12), p.3211-3215
Hauptverfasser:	DeRosha, Daniel E., Mercado, Brandon Q., Lukat‐Rodgers, Gudrun, Rodgers, Kenton R., Holland, Patrick L.
Format:	Artikel
Sprache:	eng
Schlagworte:	cobalt heterobimetallic complexes iron oxygen activation
Online-Zugang:	Volltext
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