Nitrogen‐Bridged Metallodiazaporphyrin Dimers: Synergistic Effects of Nitrogen Bridges and meso‐Nitrogen Atoms on Structure and Properties

NH‐bridged and pyrazine‐fused metallodiazaporphyrin dimers have been prepared from nickel(II) and copper(II) complexes of 3‐amino‐5,15‐diazaporphyrin by Pd‐catalyzed C−N cross‐coupling and oxidative dimerization reactions, respectively. The synergistic effects of the nitrogen bridges and meso‐nitrog...

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Veröffentlicht in:	Chemistry, an Asian journal an Asian journal, 2017-04, Vol.12 (7), p.816-821
Hauptverfasser:	Kawamata, Masahiro, Sugai, Takuma, Minoura, Mao, Maruyama, Yasuhisa, Furukawa, Ko, Holstrom, Cole, Nemykin, Victor N., Nakano, Haruyuki, Matano, Yoshihiro
Format:	Artikel
Sprache:	eng
Schlagworte:	Atoms & subatomic particles Chemistry diazaporphyrins EPR spectroscopy macrocycles Nitrogen porphyrins transition metals
Online-Zugang:	Volltext
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