Acceptorless Dehydrogenation of N‐Heterocycles by Merging Visible‐Light Photoredox Catalysis and Cobalt Catalysis

Herein, the first acceptorless dehydrogenation of tetrahydroquinolines (THQs), indolines, and other related N‐heterocycles, by merging visible‐light photoredox catalysis and cobalt catalysis at ambient temperature, is described. The potential applications to organic transformations and hydrogen‐stor...

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Veröffentlicht in:	Angewandte Chemie International Edition 2017-03, Vol.56 (11), p.3080-3084
Hauptverfasser:	He, Ke‐Han, Tan, Fang‐Fang, Zhou, Chao‐Zheng, Zhou, Gui‐Jiang, Yang, Xiao‐Long, Li, Yang
Format:	Artikel
Sprache:	eng
Schlagworte:	Ambient temperature Catalysis Cobalt Dehydrogenation heterocycles Heterocyclic compounds Hydrogen storage materials photochemistry Photoredox catalysis Quenching reaction mechanisms
Online-Zugang:	Volltext
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