Activation of CO sub(2), CS sub(2), and Dehydrogenation of Formic Acid Catalyzed by Iron(II) Hydride Complexes

Fluoroarylimine-stabilized iron(II) hydrides were used for the activation of CO sub(2). The resulting iron(II) formate complex 6, which was obtained by formal CO sub(2) insertion into the Fe-H bond, turned out to be unstable in solution. CO was suitable for the formation of stable analogues of compl...

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Veröffentlicht in:	European journal of inorganic chemistry 2016-11, Vol.2016 (33), p.5205-5214
Hauptverfasser:	Wang, Lin, Sun, Hongjian, Zuo, Zhenyu, Li, Xiaoyan, Xu, Weiqin, Langer, Robert, Fuhr, Olaf, Fenske, Dieter
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Carbon dioxide Dehydrogenation Formates Formic acid Hydrides Insertion Iron
Online-Zugang:	Volltext
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