Modulated Luminescence of a Stable Open-Shell Triarylmethyl Radical: Effects of Chemical Modification on Its Electronic Structure and Physical Properties

The open‐shell luminescent (3,5‐dichloro‐4‐pyridyl)bis(2,4,6‐trichlorophenyl)methyl (PyBTM) radical contains a nitrogen atom that behaves as a stimulus‐responsive site. Chemical modification at this nitrogen atom, such as coordination of B(C6F5)3 or methylation, shifts the emission maximum to the lo...

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Veröffentlicht in:	Chemistry : a European journal 2016-12, Vol.22 (49), p.17725-17733
Hauptverfasser:	Kusamoto, Tetsuro, Kimura, Shun, Ogino, Yasuyo, Ohde, Chie, Nishihara, Hiroshi
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Electrochemical analysis electrochemistry Electronic structure Energy levels Luminescence Molecular orbitals Nitrogen atoms Optical properties Radicals Scanning electron microscopy stimuli-responsive properties
Online-Zugang:	Volltext
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