Reaction environment and ligand lability in group 4 Cp2MXY (X, Y = Cl, OtBu) complexes

Despite their usefulness in catalytic and materials chemistry, the mixed cyclopentadienyl/alkoxide complexes of Ti, Zr, and Hf (Cp2M(OR)2) have few reliable synthetic routes available to them. We describe the use of mechanical ball milling to promote halide metathesis from Cp2MCl2, and compare these...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2016-01, Vol.45 (46), p.18635-18642
Hauptverfasser:	Boyde, Nicholas C, Rightmire, Nicholas R, Bierschenk, Eric J, Steelman, Grant W, Hanusa, Timothy P, Brennessel, William W
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkoxides Ball milling Exchange Hexanes Ligands Metathesis Solvents Titanium
Online-Zugang:	Volltext
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