Alkenylation of Arenes and Heteroarenes with Alkynes
This review is focused on the analysis of current data on new methods of alkenylation of arenes and heteroarenes with alkynes by transition metal catalyzed reactions, Bronsted/Lewis acid promoted transformations, and others. The synthetic potential, scope, limitations, and mechanistic problems of th...
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| Veröffentlicht in: | Chemical reviews 2016-05, Vol.116 (10), p.5894-5986 |
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| container_title | Chemical reviews |
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| creator | Boyarskiy, Vadim P Ryabukhin, Dmitry S Bokach, Nadezhda A Vasilyev, Aleksander V |
| description | This review is focused on the analysis of current data on new methods of alkenylation of arenes and heteroarenes with alkynes by transition metal catalyzed reactions, Bronsted/Lewis acid promoted transformations, and others. The synthetic potential, scope, limitations, and mechanistic problems of the alkenylation reactions are discussed. The insertion of an alkenyl group into aromatic and heteroaromatic rings by inter- or intramolecular ways provides a synthetic route to derivatives of styrene, stilbene, chalcone, cinnamic acid, various fused carbo- and heterocycles, etc. |
| doi_str_mv | 10.1021/acs.chemrev.5b00514 |
| format | Article |
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| ispartof | Chemical reviews, 2016-05, Vol.116 (10), p.5894-5986 |
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| source | MEDLINE; ACS Publications |
| subjects | Alkynes Alkynes - chemistry Aromatic compounds Benzofurans - chemical synthesis Benzofurans - chemistry Catalysis Chemical reactions Derivatives Heterocyclic Compounds - chemistry Indoles - chemical synthesis Indoles - chemistry Lewis acid Metals, Heavy - chemistry Quinolines - chemical synthesis Quinolines - chemistry Rings (mathematics) Styrene Transformations Transition Elements - chemistry Transition metals |
| title | Alkenylation of Arenes and Heteroarenes with Alkynes |
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