Fabrication of Zn2GeO4 nanorodsiO2 as anodes for lithium-ion batteries with enhanced cycling stability

It is known that introduction of TiO2 materials could improve cyclability of anode materials. However, such an investigation on TiO2 coating Zn2GeO4 for lithium ion batteries (LIBs) has not been reported. In this work, novel Zn2GeO4 nanorodsiO2 were fabricated. TiO2 shell layer acting as a buffer an...

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Veröffentlicht in:Materials letters 2016-12, Vol.185, p.307-310
Hauptverfasser: Peng, Xia, Zhang, Xiaozhu, Wang, Linlin, Xu, Meilan, Zhao, Daoli, Rui, Yichuan, Xu, Jingli, Tang, Kaibin
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container_end_page 310
container_issue
container_start_page 307
container_title Materials letters
container_volume 185
creator Peng, Xia
Zhang, Xiaozhu
Wang, Linlin
Xu, Meilan
Zhao, Daoli
Rui, Yichuan
Xu, Jingli
Tang, Kaibin
description It is known that introduction of TiO2 materials could improve cyclability of anode materials. However, such an investigation on TiO2 coating Zn2GeO4 for lithium ion batteries (LIBs) has not been reported. In this work, novel Zn2GeO4 nanorodsiO2 were fabricated. TiO2 shell layer acting as a buffer and mechanical support against the pulverization of the Zn2GeO4 materials improves the electrochemical properties, the Zn2GeO4 nanorodsiO2 as anode demonstrates a stable reversible capacity 330mAhg-1 after 150 cycles under a current density of 200mAg-1 and excellent rate capacity. Moreover, it is with a 100% capacity retention after the second cycle and much higher than that of compared to pure Zn2GeO4 nanorods (only 26%).
doi_str_mv 10.1016/j.matlet.2016.08.152
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subjects Anodes
Buffers
Cycles
Lithium-ion batteries
Nanorods
Nanostructure
Rechargeable batteries
Titanium dioxide
title Fabrication of Zn2GeO4 nanorodsiO2 as anodes for lithium-ion batteries with enhanced cycling stability
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