High-Pressure Synthesis of Skutterudite-Type Thermoelectric Materials
We have developed a manufacturing system by combination of high-pressure synthesis method using a multi-anvil press, and spark plasma sintering (SPS) method. By means of the system, we have succeeded in synthesizing new filled skutterudite-type thermoelectric materials MmxCo4Sb12 (Mm=mischmetal). Th...
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Veröffentlicht in: | Materials Science Forum 2016-11, Vol.879, p.1737-1742 |
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creator | Lee, Chul Ho Sekine, Chihiro Kawamura, Yukihiro Kato, Hirotaka |
description | We have developed a manufacturing system by combination of high-pressure synthesis method using a multi-anvil press, and spark plasma sintering (SPS) method. By means of the system, we have succeeded in synthesizing new filled skutterudite-type thermoelectric materials MmxCo4Sb12 (Mm=mischmetal). The thermoelectric properties of partially filled skutterudite compounds MmxCo4Sb12 synthesized under high pressure have been investigated. The Seebeck coefficient of MmxCo4Sb12 shows negative value, which means n-type conductivity. The highest dimensionless figure of merit ZT value is 0.25 for Mm0.6Co4Sb12 at 700 K. |
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By means of the system, we have succeeded in synthesizing new filled skutterudite-type thermoelectric materials MmxCo4Sb12 (Mm=mischmetal). The thermoelectric properties of partially filled skutterudite compounds MmxCo4Sb12 synthesized under high pressure have been investigated. The Seebeck coefficient of MmxCo4Sb12 shows negative value, which means n-type conductivity. 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The highest dimensionless figure of merit ZT value is 0.25 for Mm0.6Co4Sb12 at 700 K.</description><subject>Coefficients</subject><subject>Figure of merit</subject><subject>Materials science</subject><subject>Mischmetal</subject><subject>Plasma sintering</subject><subject>Presses</subject><subject>Seebeck effect</subject><subject>Spark plasma sintering</subject><subject>Synthesis</subject><subject>Thermoelectric materials</subject><subject>Thermoelectricity</subject><issn>0255-5476</issn><issn>1662-9752</issn><issn>1662-9752</issn><isbn>3035711291</isbn><isbn>9783035711295</isbn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNqNkEtLAzEUhYMPsFX_w4AL3cyYdyYrKaVVQVFoXYcxvbHRdqYmGUr_vZEKgitXZ3EP3z18CF0SXHFM6-vtdltF66FN3nlbtZCuH2fTqla6IoqpAzQgUtJSK0EP0ZBhJhQhVJMjNMBUiFJwJU_QMMZ3jBmpiRygyZ1_W5bPAWLsAxSzXZuWEH0sOlfMPvqUIPQLn6Cc7zZQzJcQ1h2swKbgbfHY5LNvVvEMHbsccP6Tp-hlOpmP78qHp9v78eihtCzvK4WUTe30ax6jHAcsmNULkFIIYZ1cCCcajZVuAHPJCadWKSWJpZToV8KUY6foas_dhO6zh5jM2kcLq1XTQtdHQ2rJhaC1YLl68af63vWhzesM5ZxLoTGvc-tm37KhizGAM5vg103YGYLNt3OTnZtf5yY7N9m5yc7Nt_NMGO0JKTRtTGCXv4_-y_gCUS6QZA</recordid><startdate>20161115</startdate><enddate>20161115</enddate><creator>Lee, Chul Ho</creator><creator>Sekine, Chihiro</creator><creator>Kawamura, Yukihiro</creator><creator>Kato, Hirotaka</creator><general>Trans Tech Publications Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7SR</scope><scope>7XB</scope><scope>88I</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>M2P</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>Q9U</scope></search><sort><creationdate>20161115</creationdate><title>High-Pressure Synthesis of Skutterudite-Type Thermoelectric Materials</title><author>Lee, Chul Ho ; 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By means of the system, we have succeeded in synthesizing new filled skutterudite-type thermoelectric materials MmxCo4Sb12 (Mm=mischmetal). The thermoelectric properties of partially filled skutterudite compounds MmxCo4Sb12 synthesized under high pressure have been investigated. The Seebeck coefficient of MmxCo4Sb12 shows negative value, which means n-type conductivity. The highest dimensionless figure of merit ZT value is 0.25 for Mm0.6Co4Sb12 at 700 K.</abstract><cop>Pfaffikon</cop><pub>Trans Tech Publications Ltd</pub><doi>10.4028/www.scientific.net/MSF.879.1737</doi><tpages>6</tpages></addata></record> |
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subjects | Coefficients Figure of merit Materials science Mischmetal Plasma sintering Presses Seebeck effect Spark plasma sintering Synthesis Thermoelectric materials Thermoelectricity |
title | High-Pressure Synthesis of Skutterudite-Type Thermoelectric Materials |
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