Development and characterization of hybrid films based on agar and alizarin red S for applications as non-enzymatic sensors for hydrogen peroxide
For the first time, the dye alizarin red S (ARS) was immobilized on indium tin oxide (ITO) electrodes via a layer-by-layer technique (LbL). This was achieved only when ARS was interspersed with the polymers agar (extracted from seaweed Gracilaria birdiae ) and PAH [poly(allylamine hydrochloride)]. A...
Gespeichert in:
| Veröffentlicht in: | Journal of materials science 2016-08, Vol.51 (15), p.7093-7107 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 7107 |
|---|---|
| container_issue | 15 |
| container_start_page | 7093 |
| container_title | Journal of materials science |
| container_volume | 51 |
| creator | de Fátima Cardoso Soares, Maria de Oliveira Farias, Emanuel Airton da Silva, Durcilene Alves Eiras, Carla |
| description | For the first time, the dye alizarin red S (ARS) was immobilized on indium tin oxide (ITO) electrodes via a layer-by-layer technique (LbL). This was achieved only when ARS was interspersed with the polymers agar (extracted from seaweed
Gracilaria birdiae
) and PAH [poly(allylamine hydrochloride)]. ARS alone did not show electroactivity when adsorbed onto ITO. Single-walled carbon nanotubes (functionalized with COOH, denoted CNTs) were used to increase the electrochemical signal of the LbL system. Interactions at the molecular level between the CNTs and other materials used in the construction of the films accounted for a threefold increase in the current signal of ARS. The films were developed as trilayer films of agar/PAH/ARS or agar(CNT)/PAH(CNT)/ARS and characterized by differential pulse voltammetry (DPV) and UV–visible spectroscopy and scanning electron microscopy. From the results, it was also possible to calculate the energy diagram for both films. The results showed that the films are promising for applications as electrochemical sensors. Accordingly, the agar(CNT)/PAH(CNT)/ARS film was tested for the reduction of hydrogen peroxide (H
2
O
2
). Under a constant potential of −0.5 V versus SCE (saturated calomel electrode), the film exhibited a rapid response for the reduction of peroxide (less than 5 s), and the current stabilized approximately at 30 s. The limit of detection for the amperometric sensor was approximately 0.15 µmol L
−1
. |
| doi_str_mv | 10.1007/s10853-016-9958-8 |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_miscellaneous_1864545027</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A452685706</galeid><sourcerecordid>A452685706</sourcerecordid><originalsourceid>FETCH-LOGICAL-c422t-4bcab02552fd836fe707932bfbdb65e148e1e91f20f03cd5c789dc22cb9842323</originalsourceid><addsrcrecordid>eNp1ks9q3DAQh01poNukD9CboJf24FQaW7Z8DOm_QCCQpGchSyOvgi25kjdk8xZ94yrrQkkh6CCY-b5hGH5F8Z7RU0Zp-zkxKnhVUtaUXcdFKV4VG8bbqqwFrV4XG0oBSqgb9qZ4m9IdpZS3wDbF7y94j2OYJ_QLUd4QvVVR6QWje1SLC54ES7b7PjpDrBunRHqV0JDcUIOKB0WNmY3Ok5gbN8SGXJ7n0enDgERUIj74Ev3jfsolTRL6FGI6kNu9iWFAT2aM4cEZPCmOrBoTvvv7Hxc_v329Pf9RXl59vzg_uyx1DbCUda9VT4FzsEZUjcWWtl0Fve1N33BktUCGHbNALa204boVndEAuu9EDRVUx8XHde4cw68dpkVOLmkcR-Ux7JJkoql5zSm0Gf3wH3oXdtHn7SQAz-fmUNFMna7UoEaUztuw5EvmZ3ByOnjM90N5VnNoBG9pk4VPz4TMLPiwDGqXkry4uX7OspXVMaQU0co5uknFvWRUPiVArgmQOQHyKQFSZAdWJ2XWDxj_rf2y9Ae-pbSc</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2259585230</pqid></control><display><type>article</type><title>Development and characterization of hybrid films based on agar and alizarin red S for applications as non-enzymatic sensors for hydrogen peroxide</title><source>SpringerLink Journals</source><creator>de Fátima Cardoso Soares, Maria ; de Oliveira Farias, Emanuel Airton ; da Silva, Durcilene Alves ; Eiras, Carla</creator><creatorcontrib>de Fátima Cardoso Soares, Maria ; de Oliveira Farias, Emanuel Airton ; da Silva, Durcilene Alves ; Eiras, Carla</creatorcontrib><description>For the first time, the dye alizarin red S (ARS) was immobilized on indium tin oxide (ITO) electrodes via a layer-by-layer technique (LbL). This was achieved only when ARS was interspersed with the polymers agar (extracted from seaweed
Gracilaria birdiae
) and PAH [poly(allylamine hydrochloride)]. ARS alone did not show electroactivity when adsorbed onto ITO. Single-walled carbon nanotubes (functionalized with COOH, denoted CNTs) were used to increase the electrochemical signal of the LbL system. Interactions at the molecular level between the CNTs and other materials used in the construction of the films accounted for a threefold increase in the current signal of ARS. The films were developed as trilayer films of agar/PAH/ARS or agar(CNT)/PAH(CNT)/ARS and characterized by differential pulse voltammetry (DPV) and UV–visible spectroscopy and scanning electron microscopy. From the results, it was also possible to calculate the energy diagram for both films. The results showed that the films are promising for applications as electrochemical sensors. Accordingly, the agar(CNT)/PAH(CNT)/ARS film was tested for the reduction of hydrogen peroxide (H
2
O
2
). Under a constant potential of −0.5 V versus SCE (saturated calomel electrode), the film exhibited a rapid response for the reduction of peroxide (less than 5 s), and the current stabilized approximately at 30 s. The limit of detection for the amperometric sensor was approximately 0.15 µmol L
−1
.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-016-9958-8</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Agar ; Alizarin ; Calomel electrode ; Carbon nanotubes ; Characterization and Evaluation of Materials ; Chemical properties ; Chemical sensors ; Chemistry and Materials Science ; Classical Mechanics ; Crystallography and Scattering Methods ; Electric properties ; Electrical measurement ; Electroactivity ; Electrodes ; Enzymes ; Hydrogen peroxide ; Indium ; Indium tin oxide ; Indium tin oxides ; Materials Science ; Nanotubes ; Original Paper ; Polyallylamine hydrochloride ; Polymer Sciences ; Reduction ; Scanning electron microscopy ; Seaweeds ; Sensors ; Single wall carbon nanotubes ; Solid Mechanics ; Spectrum analysis</subject><ispartof>Journal of materials science, 2016-08, Vol.51 (15), p.7093-7107</ispartof><rights>Springer Science+Business Media New York 2016</rights><rights>COPYRIGHT 2016 Springer</rights><rights>Journal of Materials Science is a copyright of Springer, (2016). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c422t-4bcab02552fd836fe707932bfbdb65e148e1e91f20f03cd5c789dc22cb9842323</citedby><cites>FETCH-LOGICAL-c422t-4bcab02552fd836fe707932bfbdb65e148e1e91f20f03cd5c789dc22cb9842323</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-016-9958-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-016-9958-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>de Fátima Cardoso Soares, Maria</creatorcontrib><creatorcontrib>de Oliveira Farias, Emanuel Airton</creatorcontrib><creatorcontrib>da Silva, Durcilene Alves</creatorcontrib><creatorcontrib>Eiras, Carla</creatorcontrib><title>Development and characterization of hybrid films based on agar and alizarin red S for applications as non-enzymatic sensors for hydrogen peroxide</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>For the first time, the dye alizarin red S (ARS) was immobilized on indium tin oxide (ITO) electrodes via a layer-by-layer technique (LbL). This was achieved only when ARS was interspersed with the polymers agar (extracted from seaweed
Gracilaria birdiae
) and PAH [poly(allylamine hydrochloride)]. ARS alone did not show electroactivity when adsorbed onto ITO. Single-walled carbon nanotubes (functionalized with COOH, denoted CNTs) were used to increase the electrochemical signal of the LbL system. Interactions at the molecular level between the CNTs and other materials used in the construction of the films accounted for a threefold increase in the current signal of ARS. The films were developed as trilayer films of agar/PAH/ARS or agar(CNT)/PAH(CNT)/ARS and characterized by differential pulse voltammetry (DPV) and UV–visible spectroscopy and scanning electron microscopy. From the results, it was also possible to calculate the energy diagram for both films. The results showed that the films are promising for applications as electrochemical sensors. Accordingly, the agar(CNT)/PAH(CNT)/ARS film was tested for the reduction of hydrogen peroxide (H
2
O
2
). Under a constant potential of −0.5 V versus SCE (saturated calomel electrode), the film exhibited a rapid response for the reduction of peroxide (less than 5 s), and the current stabilized approximately at 30 s. The limit of detection for the amperometric sensor was approximately 0.15 µmol L
−1
.</description><subject>Agar</subject><subject>Alizarin</subject><subject>Calomel electrode</subject><subject>Carbon nanotubes</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical properties</subject><subject>Chemical sensors</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Crystallography and Scattering Methods</subject><subject>Electric properties</subject><subject>Electrical measurement</subject><subject>Electroactivity</subject><subject>Electrodes</subject><subject>Enzymes</subject><subject>Hydrogen peroxide</subject><subject>Indium</subject><subject>Indium tin oxide</subject><subject>Indium tin oxides</subject><subject>Materials Science</subject><subject>Nanotubes</subject><subject>Original Paper</subject><subject>Polyallylamine hydrochloride</subject><subject>Polymer Sciences</subject><subject>Reduction</subject><subject>Scanning electron microscopy</subject><subject>Seaweeds</subject><subject>Sensors</subject><subject>Single wall carbon nanotubes</subject><subject>Solid Mechanics</subject><subject>Spectrum analysis</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1ks9q3DAQh01poNukD9CboJf24FQaW7Z8DOm_QCCQpGchSyOvgi25kjdk8xZ94yrrQkkh6CCY-b5hGH5F8Z7RU0Zp-zkxKnhVUtaUXcdFKV4VG8bbqqwFrV4XG0oBSqgb9qZ4m9IdpZS3wDbF7y94j2OYJ_QLUd4QvVVR6QWje1SLC54ES7b7PjpDrBunRHqV0JDcUIOKB0WNmY3Ok5gbN8SGXJ7n0enDgERUIj74Ev3jfsolTRL6FGI6kNu9iWFAT2aM4cEZPCmOrBoTvvv7Hxc_v329Pf9RXl59vzg_uyx1DbCUda9VT4FzsEZUjcWWtl0Fve1N33BktUCGHbNALa204boVndEAuu9EDRVUx8XHde4cw68dpkVOLmkcR-Ux7JJkoql5zSm0Gf3wH3oXdtHn7SQAz-fmUNFMna7UoEaUztuw5EvmZ3ByOnjM90N5VnNoBG9pk4VPz4TMLPiwDGqXkry4uX7OspXVMaQU0co5uknFvWRUPiVArgmQOQHyKQFSZAdWJ2XWDxj_rf2y9Ae-pbSc</recordid><startdate>20160801</startdate><enddate>20160801</enddate><creator>de Fátima Cardoso Soares, Maria</creator><creator>de Oliveira Farias, Emanuel Airton</creator><creator>da Silva, Durcilene Alves</creator><creator>Eiras, Carla</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20160801</creationdate><title>Development and characterization of hybrid films based on agar and alizarin red S for applications as non-enzymatic sensors for hydrogen peroxide</title><author>de Fátima Cardoso Soares, Maria ; de Oliveira Farias, Emanuel Airton ; da Silva, Durcilene Alves ; Eiras, Carla</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c422t-4bcab02552fd836fe707932bfbdb65e148e1e91f20f03cd5c789dc22cb9842323</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Agar</topic><topic>Alizarin</topic><topic>Calomel electrode</topic><topic>Carbon nanotubes</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical properties</topic><topic>Chemical sensors</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Crystallography and Scattering Methods</topic><topic>Electric properties</topic><topic>Electrical measurement</topic><topic>Electroactivity</topic><topic>Electrodes</topic><topic>Enzymes</topic><topic>Hydrogen peroxide</topic><topic>Indium</topic><topic>Indium tin oxide</topic><topic>Indium tin oxides</topic><topic>Materials Science</topic><topic>Nanotubes</topic><topic>Original Paper</topic><topic>Polyallylamine hydrochloride</topic><topic>Polymer Sciences</topic><topic>Reduction</topic><topic>Scanning electron microscopy</topic><topic>Seaweeds</topic><topic>Sensors</topic><topic>Single wall carbon nanotubes</topic><topic>Solid Mechanics</topic><topic>Spectrum analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>de Fátima Cardoso Soares, Maria</creatorcontrib><creatorcontrib>de Oliveira Farias, Emanuel Airton</creatorcontrib><creatorcontrib>da Silva, Durcilene Alves</creatorcontrib><creatorcontrib>Eiras, Carla</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>de Fátima Cardoso Soares, Maria</au><au>de Oliveira Farias, Emanuel Airton</au><au>da Silva, Durcilene Alves</au><au>Eiras, Carla</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Development and characterization of hybrid films based on agar and alizarin red S for applications as non-enzymatic sensors for hydrogen peroxide</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2016-08-01</date><risdate>2016</risdate><volume>51</volume><issue>15</issue><spage>7093</spage><epage>7107</epage><pages>7093-7107</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>For the first time, the dye alizarin red S (ARS) was immobilized on indium tin oxide (ITO) electrodes via a layer-by-layer technique (LbL). This was achieved only when ARS was interspersed with the polymers agar (extracted from seaweed
Gracilaria birdiae
) and PAH [poly(allylamine hydrochloride)]. ARS alone did not show electroactivity when adsorbed onto ITO. Single-walled carbon nanotubes (functionalized with COOH, denoted CNTs) were used to increase the electrochemical signal of the LbL system. Interactions at the molecular level between the CNTs and other materials used in the construction of the films accounted for a threefold increase in the current signal of ARS. The films were developed as trilayer films of agar/PAH/ARS or agar(CNT)/PAH(CNT)/ARS and characterized by differential pulse voltammetry (DPV) and UV–visible spectroscopy and scanning electron microscopy. From the results, it was also possible to calculate the energy diagram for both films. The results showed that the films are promising for applications as electrochemical sensors. Accordingly, the agar(CNT)/PAH(CNT)/ARS film was tested for the reduction of hydrogen peroxide (H
2
O
2
). Under a constant potential of −0.5 V versus SCE (saturated calomel electrode), the film exhibited a rapid response for the reduction of peroxide (less than 5 s), and the current stabilized approximately at 30 s. The limit of detection for the amperometric sensor was approximately 0.15 µmol L
−1
.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-016-9958-8</doi><tpages>15</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-2461 |
| ispartof | Journal of materials science, 2016-08, Vol.51 (15), p.7093-7107 |
| issn | 0022-2461 1573-4803 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1864545027 |
| source | SpringerLink Journals |
| subjects | Agar Alizarin Calomel electrode Carbon nanotubes Characterization and Evaluation of Materials Chemical properties Chemical sensors Chemistry and Materials Science Classical Mechanics Crystallography and Scattering Methods Electric properties Electrical measurement Electroactivity Electrodes Enzymes Hydrogen peroxide Indium Indium tin oxide Indium tin oxides Materials Science Nanotubes Original Paper Polyallylamine hydrochloride Polymer Sciences Reduction Scanning electron microscopy Seaweeds Sensors Single wall carbon nanotubes Solid Mechanics Spectrum analysis |
| title | Development and characterization of hybrid films based on agar and alizarin red S for applications as non-enzymatic sensors for hydrogen peroxide |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T00%3A41%3A25IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_proqu&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Development%20and%20characterization%20of%20hybrid%20films%20based%20on%20agar%20and%20alizarin%20red%20S%20for%20applications%20as%20non-enzymatic%20sensors%20for%20hydrogen%20peroxide&rft.jtitle=Journal%20of%20materials%20science&rft.au=de%20F%C3%A1tima%20Cardoso%20Soares,%20Maria&rft.date=2016-08-01&rft.volume=51&rft.issue=15&rft.spage=7093&rft.epage=7107&rft.pages=7093-7107&rft.issn=0022-2461&rft.eissn=1573-4803&rft_id=info:doi/10.1007/s10853-016-9958-8&rft_dat=%3Cgale_proqu%3EA452685706%3C/gale_proqu%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2259585230&rft_id=info:pmid/&rft_galeid=A452685706&rfr_iscdi=true |