p-Bromoaryl- and ω-bromoalkyl-VA-PNBs: suitable starting materials for the functionalization of vinylic addition polynorbornenes via palladium-catalyzed cross-coupling reactions

New vinylic addition polynorbornenes (VA-PNBs) with a variable amount of pendant 4-bromoaryl groups have been synthesized by homo- and copolymerization with norbornene of 2-(4-bromophenyl)-5-norbornene catalyzed by [Ni(C 6 F 5 ) 2 (SbPh 3 ) 2 ]. These polymers can be transformed by Pd-catalyzed cros...

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Veröffentlicht in:	RSC advances 2016-01, Vol.6 (107), p.105878-105887
Hauptverfasser:	Martínez-Arranz, Sheila, Sánchez-Pérez, Eduardo, Molina de la Torre, Jesús A., Pérez-Ortega, Ignacio, Albéniz, Ana C.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical reactions Copolymerization Cross coupling Palladium Synthesis (chemistry) Thermal stability
Online-Zugang:	Volltext
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