Development of highly-sensitive detection system in 19F NMR for bioactive compounds based on the assembly of paramagnetic complexes with fluorinated cubic silsesquioxanes

[Display omitted] This manuscript reports the detection system with 19F NMR probes for bioactive amine compounds at sub-micro molar concentrations. Water-soluble fluorinated polyhedral oligomeric silsesquioxane (POSS) derivatives were prepared, and the paramagnetic Ni-porphyrin (NiPor) with the fluo...

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Veröffentlicht in:	Bioorganic & medicinal chemistry 2017-02, Vol.25 (4), p.1389-1393
Hauptverfasser:	Kakuta, Takahiro, Narikiyo, Hayato, Jeon, Jong-Hwan, Tanaka, Kazuo, Chujo, Yoshiki
Format:	Artikel
Sprache:	eng
Schlagworte:	19F NMR Fluorinated compound Molecular probe Paramagnetic relaxation enhancement Silsesquioxane
Online-Zugang:	Volltext
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