Synthesis and Electron Paramagnetic Resonance Studies of Oligodeoxynucleotides Containing 2-N-tert-Butylaminoxyl-2′-deoxyadenosines

Oligodeoxynucleotides (ODNs) containing 2‐N‐tert‐butylaminoxyl‐2′‐deoxyadenosine (A*) residues were synthesized to allow accurate monitoring of adenine motion by EPR spectroscopy through the agency of direct linkage of the acyclic aminoxyl group to the nucleobase, and EPR studies of the ODNs in sing...

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Veröffentlicht in:	Chembiochem : a European journal of chemical biology 2016-12, Vol.17 (24), p.2346-2352
Hauptverfasser:	Kurita, Manami, Higuchi, Yoshitaka, Mirc, JW, Matsumoto, Shintaro, Usui, Kazuteru, Suemune, Hiroshi, Aso, Mariko
Format:	Artikel
Sprache:	eng
Schlagworte:	aminoxyl radicals Base Sequence Deoxyadenosines - chemistry DNA structures Electron Spin Resonance Spectroscopy EPR spectroscopy Nucleic Acid Hybridization nucleic acids Oligodeoxyribonucleotides - chemical synthesis Oligodeoxyribonucleotides - chemistry Spectrum analysis Spin Labels spin-labeled nucleosides
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