Ligand Bite Angle Effects in Metal-catalyzed C−C Bond Formation

Ligand Bite Angle Effects in Metal-catalyzed C−C Bond Formation

Van Leeuwen et al summarize the effect of the bite angle of bidentate ligands on the catalytic formation of carbon-to-carbon bonds. Their data show that the bite angle of bidentate ligands is an important parameter that has a pronounced effect on rate and selectivity of metal-catalyzed reactions.

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Veröffentlicht in:Chemical reviews 2000-08, Vol.100 (8), p.2741-2770
Hauptverfasser: van Leeuwen, Piet W. N. M, Kamer, Paul C. J, Reek, Joost N. H, Dierkes, Peter
Format: Artikel
Sprache:eng
Schlagworte:
Catalysts
Chemical reactions
Chemistry
Metals
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Zusammenfassung:Van Leeuwen et al summarize the effect of the bite angle of bidentate ligands on the catalytic formation of carbon-to-carbon bonds. Their data show that the bite angle of bidentate ligands is an important parameter that has a pronounced effect on rate and selectivity of metal-catalyzed reactions.
ISSN:0009-2665
1520-6890
DOI:10.1021/cr9902704