Activation of Ligand Reactivity:  Thiolate C−S and Dithiophosphate Ester C−O Heterolyses within a Dimolybdenum(V) System

Ligand reactivity was demonstrated for sulfide alkylation, thiolate dealkylation, and dithiophosphate de-esterification within molybdenum(V) dimers. The cationic complex [Mo2(NC6H4Me)2(S2P(OEt)2)2(μ-O2CMe)(μ-SR)2]+ was inductively activated toward thiolate C−S and dithiophosphate C−O heterolyses. Th...

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Veröffentlicht in:	Inorganic chemistry 1999-02, Vol.38 (4), p.802-813
Hauptverfasser:	Koffi-Sokpa, Edith I, Calfee, D. Troy, Allred, Brian R. T, Davis, Jackie L, Haub, Elaine K, Rich, Alexis K, Porter, Richard A, Mashuta, Mark S, Richardson, John F, Noble, Mark E
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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