Preparation and Characterization of a Diamagnetic and Dinuclear Titanium(III) Formamidinate Complex. Evidence for the Existence of a Ti−Ti Bond?

The new diamagnetic Ti(III) complex (CyNC(H)NCy)4Ti2Cl2·2THF (1) containing a short Ti−Ti distance was prepared and crystallographically characterized. Ab initio unrestricted Hartree−Fock calculations suggested the presence of a Ti−Ti bonding interaction. Crystal data for 1 are as follows:  C60H108N...

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Veröffentlicht in:	Inorganic chemistry 1997-04, Vol.36 (9), p.1745-1748
Hauptverfasser:	Hao, Shoukang, Feghali, Khalil, Gambarotta, Sandro
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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