Iron−Manganese Redox Processes and Synergism in the Mechanism for Manganese-Catalyzed Autoxidation of Hydrogen Sulfite

The mechanism for manganese-catalyzed aqueous autoxidation of hydrogen sulfite at pH 2.4 has been revised on the basis of previous comprehensive kinetic studies and thermodynamic data for iron−manganese redox processes and manganese(II) and -(III) protolysis equilibria. The catalytically active mang...

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Veröffentlicht in:	Inorganic chemistry 1998-09, Vol.37 (19), p.4939-4944
Hauptverfasser:	Fronaeus, Sture, Berglund, Johan, Elding, Lars I
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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