Molecular Assemblies Containing Unsupported [FeIII−(μ2:η2-RCO2)−CuII] Bridges

Formate is an inhibitor of cytochrome oxidases and also effects conversion of the bovine heart enzyme from the “fast” to the “slow” cyanide-binding form. The molecular basis of these effects is unknown; one possibility is that formate inserts as a bridge into the binuclear heme a 3−CuB site, impedin...

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Veröffentlicht in:	Inorganic chemistry 1996-04, Vol.35 (9), p.2558-2567
Hauptverfasser:	Scott, Michael J, Goddard, Christine A, Holm, R. H
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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