Regio- and Stereochemical Aspects of the Palladium-Catalyzed Desilylation−Arylation of Substituted Vinylsilanes

The palladium-catalyzed desilylation−arylation of substituted vinylsilanes by p-iodoanisole in the presence of bidentate phosphine ligands is described. Apart from enhancing the rate of the reaction considerably, heteroatom-based functional groups in the vinylsilane moiety have a profound influence...

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Veröffentlicht in:	Journal of organic chemistry 1996-10, Vol.61 (20), p.7139-7146
Hauptverfasser:	Alvisi, Davide, Blart, Errol, Bonini, Bianca Flavia, Mazzanti, Germana, Ricci, Alfredo, Zani, Paolo
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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