Syntheses and Structural Characterization of Tetrahedral Four-Coordinate Gold(I) Complexes of 1,3,5-Triaza-7-phosphaadamantane. An Example of a Hydrogen-Bond-Directed Supramolecular Assembly

The synthesis and structural characterization of water-soluble four-coordinate gold(I) complexes containing monodentate phosphine ligands are described. The ligands used are 1,3,5-triaza-7-phosphaadamantane (TPA) and its protonated and methylated derivatives, [HTPA]Cl and [MeTPA]I. Formation of the...

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Veröffentlicht in:Inorganic chemistry 1996-01, Vol.35 (1), p.16-22
Hauptverfasser: Forward, Jennifer M, Assefa, Zerihun, Staples, Richard J, Fackler, John P
Format: Artikel
Sprache:eng
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