Molecular Recognition of Activated and Unactivated Phosphate Diesters

The molecular recognition of two simple phosphate diesters by a terpyridine−copper (TCu) complex was studied by X-ray crystallography and potentiometry. Molecular recognition of the substrate is the first step in a hydrolysis reaction. The two phosphate diesters bis(p-nitrophenyl) phosphate (BNP) an...

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Veröffentlicht in:Inorganic chemistry 1999-12, Vol.38 (26), p.6003-6007
Hauptverfasser: Jurek, Paul E, Martell, Arthur E
Format: Artikel
Sprache:eng
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