Imido Complexes Derived from the Reactions of Niobium and Tantalum Pentachlorides with Primary Amines:  Relevance to the Chemical Vapor Deposition of Metal Nitride Films

Reactions of niobium and tantalum pentachlorides with tert-butylamine (≥6 equiv) in benzene afford the dimeric imido complexes [NbCl2(NtBu)(NHtBu)(NH2 tBu)]2 (90%) and [TaCl2(NtBu)(NHtBu)(NH2 tBu)]2 (79%). The niobium complex exists as two isomers in solution, while the tantalum complex is composed...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Inorganic chemistry 1996-08, Vol.35 (17), p.4910-4920
Hauptverfasser:	Jayaratne, Kumudini C, Yap, Glenn P. A, Haggerty, Brian S, Rheingold, Arnold L, Winter, Charles H
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!