Asymmetric Synthesis of P-Chiral Diphosphines. Steric Effects on the Palladium-Complex-Promoted Asymmetric Diels−Alder Reaction between a Dimethylphenylphosphole and (E/Z)-Methyl-Substituted Diphenylvinylphosphines

The organopalladium complex containing ortho-metalated (S)-(1-(dimethylamino)ethyl)naphthalene as the chiral auxiliary has been used successfully to promote the asymmetric [4+2] Diels−Alder reactions between 1-phenyl-3,4-dimethylphosphole and the following coordinated dienophiles:  (a) diphenylvinyl...

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Veröffentlicht in:	Inorganic chemistry 1997-05, Vol.36 (10), p.2138-2146
Hauptverfasser:	Aw, Beng-Hwee, Hor, T. S. Andy, Selvaratnam, S., Mok, K. F., White, Andrew J. P., Williams, David J., Rees, Nicholas H., McFarlane, William, Leung, Pak-Hing
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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