Volume Profile for Substitution in Labile Chromium(III) Complexes:  Reactions of Aqueous [Cr(Hedta)OH2] and [Cr(edta)]- with Thiocyanate Ion

A procedure is given for correcting optical absorbance measurements made at variable pressure with a le Noble−Schlott (“pillbox”) cell for the inner sleeve wall thickness. With this technique, the molar volume change for the acid ionization of aqueous [Cr(Hedta)OH2] was found to be +5.1 ± 0.6 cm3 mo...

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Veröffentlicht in:	Inorganic chemistry 1996-02, Vol.35 (4), p.991-994
Hauptverfasser:	Beswick, Colin L, Shalders, Richard D, Swaddle, Thomas W
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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