The Type 2 Intramolecular Diels-Alder Reaction: Synthesis and Chemistry of Bridgehead Alkenes

Anti‐Bredt alkenes, bicyclic molecules that contain a bridgehead double bond, were for many years regarded as chemical curiosities. The type 2 intramolecular Diels–Alder (IMDA) reaction provides a one‐step entry into this fascinating class of molecules. The reaction has made available numerous anti‐...

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Veröffentlicht in:	Angewandte Chemie International Edition 2001-03, Vol.40 (5), p.820-849
Hauptverfasser:	Bear, Brian R., Sparks, Steven M., Shea, Kenneth J.
Format:	Artikel
Sprache:	eng
Schlagworte:	bridgehead alkenes cycloaddition natural products strained molecules synthetic methods
Online-Zugang:	Volltext
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