Hyperbolic Spirals as Surface Structures in Thin Layers

When thin layers of 4-chloro-3-methylphenol and a copolymer of methyl(methacrylate) and maleic acid dissolved in acetone are dried by solvent evaporation, various surface structures appear. Besides linear surface deformations that can ramify like fractals, spirals of the hyperbolic type have been fo...

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Veröffentlicht in:Journal of colloid and interface science 2001-03, Vol.235 (2), p.210-217
1. Verfasser: Weh, Lothar
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description When thin layers of 4-chloro-3-methylphenol and a copolymer of methyl(methacrylate) and maleic acid dissolved in acetone are dried by solvent evaporation, various surface structures appear. Besides linear surface deformations that can ramify like fractals, spirals of the hyperbolic type have been found. The surface structures are due to crystallization processes and flows caused by surface tension differences. The spirals are surface elevations with grooves on both sides as shown by surface profile measurements by means of a microscope interferometer. The addition of surfactants reduces the structure formation. A large surfactant concentration prevents the structure formation.
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subjects Chemistry
Colloidal state and disperse state
crystallization
Exact sciences and technology
Gas-liquid interface and liquid-liquid interface
General and physical chemistry
Marangoni effect
Micelles. Thin films
spiral structures
surface flow
Surface physical chemistry
surface tension
title Hyperbolic Spirals as Surface Structures in Thin Layers
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