Asymmetric PTC C-Alkylation Catalyzed by Chiral Derivatives of Tartaric Acid and Aminophenols. Synthesis of (R)- and (S)-α-Methyl Amino Acids

A new type of efficient chiral catalyst has been elaborated for asymmetric C-alkylation of CH acids under PTC conditions. Sodium alkoxides formed from chiral derivatives of tartaric acid and aminophenols (TADDOL's 2a−e and NOBIN's 3a−h) can be used as chiral catalysts in the enantioselecti...

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Veröffentlicht in:	Journal of organic chemistry 2000-10, Vol.65 (21), p.7041-7048
Hauptverfasser:	Belokon, Yuri N, Kochetkov, Konstantin A, Churkina, Tatiana D, Ikonnikov, Nikolai S, Chesnokov, Alexey A, Larionov, Oleg V, Singh, Ishwar, Parmar, Virinder S, Vyskočil, Šťepán, Kagan, Henri B
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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