Titanocene-Catalyzed Carbosilylation of Alkenes and Dienes Using Alkyl Halides and Chlorosilanes

A new method for regioselective carbosilylation of alkenes and dienes has been developed by the use of a titanocene catalyst. This reaction proceeds efficiently at 0 °C in THF in the presence of Grignard reagents by the combined use of alkyl halides (R‘−X, X = Br or Cl) and chlorotrialkylsilanes (R3...

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Veröffentlicht in:	Journal of organic chemistry 2000-08, Vol.65 (17), p.5291-5297
Hauptverfasser:	Nii, Shinsuke, Terao, Jun, Kambe, Nobuaki
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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