Polymeric aqua(glutarato)(hydrogen glutarato)lanthanum(III) monohydrate
The structure of the title compound, [La(C5H6O4)(C5H7O4)‐(H2O)]·H2O, consists of dense layers formed by chains of one‐edge‐sharing LaO9(H2O) polyhedra, linked together by the glutarate ligand. The three‐dimensional polymeric structure, built up through connection of these layers by the hydrogen glut...
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| Veröffentlicht in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2000-07, Vol.56 (7), p.789-792 |
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| container_title | Acta crystallographica. Section C, Crystal structure communications |
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| creator | Benmerad, Belkacem Guehria-Laidoudi, Achoura Balegroune, Fadila Birkedal, Henrik Chapuis, Gervais |
| description | The structure of the title compound, [La(C5H6O4)(C5H7O4)‐(H2O)]·H2O, consists of dense layers formed by chains of one‐edge‐sharing LaO9(H2O) polyhedra, linked together by the glutarate ligand. The three‐dimensional polymeric structure, built up through connection of these layers by the hydrogen glutarate ligand, exhibits cavities accommodating a guest water molecule. The lanthanum ion is tenfold coordinated by four glutarates, acting as bridging–chelating carboxylate groups, by three hydrogen glutarates, three times monodentate, and by one water molecule. Its coordination polyhedron is highly distorted and intermediate between a bicapped dodecahedron and a tetracapped trigonal prism. Hydrogen bonding links the two water molecules and the framework built up from this polynuclear coordination polymer. A very short hydrogen bond, D⋯A = 2.484 (3) Å, links the protonated with the deprotonated acid groups in the hydrogen glutarate. |
| doi_str_mv | 10.1107/S010827010000500X |
| format | Article |
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The three‐dimensional polymeric structure, built up through connection of these layers by the hydrogen glutarate ligand, exhibits cavities accommodating a guest water molecule. The lanthanum ion is tenfold coordinated by four glutarates, acting as bridging–chelating carboxylate groups, by three hydrogen glutarates, three times monodentate, and by one water molecule. Its coordination polyhedron is highly distorted and intermediate between a bicapped dodecahedron and a tetracapped trigonal prism. Hydrogen bonding links the two water molecules and the framework built up from this polynuclear coordination polymer. 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Section C, Crystal structure communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Benmerad, Belkacem</au><au>Guehria-Laidoudi, Achoura</au><au>Balegroune, Fadila</au><au>Birkedal, Henrik</au><au>Chapuis, Gervais</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polymeric aqua(glutarato)(hydrogen glutarato)lanthanum(III) monohydrate</atitle><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle><addtitle>Acta Cryst. C</addtitle><date>2000-07</date><risdate>2000</risdate><volume>56</volume><issue>7</issue><spage>789</spage><epage>792</epage><pages>789-792</pages><issn>0108-2701</issn><eissn>1600-5759</eissn><coden>ACSCEE</coden><abstract>The structure of the title compound, [La(C5H6O4)(C5H7O4)‐(H2O)]·H2O, consists of dense layers formed by chains of one‐edge‐sharing LaO9(H2O) polyhedra, linked together by the glutarate ligand. 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| ispartof | Acta crystallographica. Section C, Crystal structure communications, 2000-07, Vol.56 (7), p.789-792 |
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| source | Crystallography Journals Online; Wiley Online Library Journals Frontfile Complete |
| subjects | Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Inorganic compounds Metal complexes Physics Structure of solids and liquids crystallography Structure of specific crystalline solids |
| title | Polymeric aqua(glutarato)(hydrogen glutarato)lanthanum(III) monohydrate |
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