Polymeric Layers Catenated by Ribbons of Rings in a Three-Dimensional Self-Assembled Architecture: A Nanoporous Network with Spongelike Behavior

Polymeric Layers Catenated by Ribbons of Rings in a Three-Dimensional Self-Assembled Architecture: A Nanoporous Network with Spongelike Behavior

The peculiar spongelike behavior of the nanoporous crystal, composed from the self‐assembly of copper(II) sulfate and 1,3‐bis(4‐pyridyl)propane, is derived from its unusual topology: an architecture comprising two different structural motifs. The supramolecular catenation (see the picture) features...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2000-04, Vol.39 (8), p.1506-1510
Hauptverfasser: Carlucci, Lucia, Ciani, Gianfranco, Moret, Massimo, Proserpio, Davide M., Rizzato, Silvia
Format: Artikel
Sprache:eng
Schlagworte:
coordination polymers
copper
layered compounds
N ligands
nanostructures
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The peculiar spongelike behavior of the nanoporous crystal, composed from the self‐assembly of copper(II) sulfate and 1,3‐bis(4‐pyridyl)propane, is derived from its unusual topology: an architecture comprising two different structural motifs. The supramolecular catenation (see the picture) features ribbons‐of‐rings interpenetrating and entangling (4,4) layers.
ISSN:1433-7851
1521-3773
DOI:10.1002/(SICI)1521-3773(20000417)39:8<1506::AID-ANIE1506>3.0.CO;2-U