A Robust, Environmentally Benign Catalyst for Highly Selective Hydroformylation

By a sol–gel process a rhodium complex containing a diphosphane with a large natural P‐Rh‐P bite angle is covalently anchored in a silica matrix (see picture). The immobilized catalyst is a very selective hydroformylation catalyst that is completely and conveniently separated from the product and ca...

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Veröffentlicht in:	Angewandte Chemie International Edition 1999-11, Vol.38 (21), p.3231-3235
Hauptverfasser:	Sandee, Albertus J., van der Veen, Lars A., Reek, Joost N. H., Kamer, Paul C. J., Lutz, Martin, Spek, Anthony L., van Leeuwen, Piet W. N. M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysts Covalence Hydroformylations Immobilization Pictures Rhodium Silicon dioxide Sol gel process Sol-gel processes
Online-Zugang:	Volltext
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