A Robust, Environmentally Benign Catalyst for Highly Selective Hydroformylation
By a sol–gel process a rhodium complex containing a diphosphane with a large natural P‐Rh‐P bite angle is covalently anchored in a silica matrix (see picture). The immobilized catalyst is a very selective hydroformylation catalyst that is completely and conveniently separated from the product and ca...
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| Veröffentlicht in: | Angewandte Chemie International Edition 1999-11, Vol.38 (21), p.3231-3235 |
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| container_end_page | 3235 |
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| container_issue | 21 |
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| container_title | Angewandte Chemie International Edition |
| container_volume | 38 |
| creator | Sandee, Albertus J. van der Veen, Lars A. Reek, Joost N. H. Kamer, Paul C. J. Lutz, Martin Spek, Anthony L. van Leeuwen, Piet W. N. M. |
| description | By a sol–gel process a rhodium complex containing a diphosphane with a large natural P‐Rh‐P bite angle is covalently anchored in a silica matrix (see picture). The immobilized catalyst is a very selective hydroformylation catalyst that is completely and conveniently separated from the product and can be reused in numerous cycles. |
| doi_str_mv | 10.1002/(SICI)1521-3773(19991102)38:21<3231::AID-ANIE3231>3.0.CO;2-B |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie International Edition, 1999-11, Vol.38 (21), p.3231-3235 |
| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1859316711 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Catalysts Covalence Hydroformylations Immobilization Pictures Rhodium Silicon dioxide Sol gel process Sol-gel processes |
| title | A Robust, Environmentally Benign Catalyst for Highly Selective Hydroformylation |
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