Rotational Spectrum of CBr by Kinetic Microwave Spectroscopy of 193-nm Photolysis Products of Bromoform

We have measured the first millimeter-wave spectrum of CBr. The radical was produced by pulsed UV–laser photolysis of bromoform at 193 nm and detected using kinetic spectroscopy. We have significantly improved the rotational and fine structure constants for the ground vibrational state. The hyperfin...

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Veröffentlicht in:	Journal of molecular spectroscopy 2000-03, Vol.200 (1), p.16-24
Hauptverfasser:	Hassouna, M., Walters, A., Demuynck, C., Bogey, M.
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Sprache:	eng
Schlagworte:	bromoform CBr excimer laser kinetic microwave photolysis rotational spectra
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creator	Hassouna, M. Walters, A. Demuynck, C. Bogey, M.
description	We have measured the first millimeter-wave spectrum of CBr. The radical was produced by pulsed UV–laser photolysis of bromoform at 193 nm and detected using kinetic spectroscopy. We have significantly improved the rotational and fine structure constants for the ground vibrational state. The hyperfine structure due to the bromine nucleus has been resolved and quadrupole and magnetic hyperfine parameters evaluated for the first time.
doi_str_mv	10.1006/jmsp.1999.8030
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The hyperfine structure due to the bromine nucleus has been resolved and quadrupole and magnetic hyperfine parameters evaluated for the first time.</description><identifier>ISSN: 0022-2852</identifier><identifier>EISSN: 1096-083X</identifier><identifier>DOI: 10.1006/jmsp.1999.8030</identifier><identifier>PMID: 10662572</identifier><language>eng</language><publisher>United States: Elsevier Inc</publisher><subject>bromoform ; CBr ; excimer laser ; kinetic ; microwave ; photolysis ; rotational spectra</subject><ispartof>Journal of molecular spectroscopy, 2000-03, Vol.200 (1), p.16-24</ispartof><rights>2000 Academic Press</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c342t-2645a2ebe54093868e4e458fc0f7212f4ecefe6d4c6e289a702991d1a9b71af53</citedby><cites>FETCH-LOGICAL-c342t-2645a2ebe54093868e4e458fc0f7212f4ecefe6d4c6e289a702991d1a9b71af53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S002228529998030X$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/10662572$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Hassouna, M.</creatorcontrib><creatorcontrib>Walters, A.</creatorcontrib><creatorcontrib>Demuynck, C.</creatorcontrib><creatorcontrib>Bogey, M.</creatorcontrib><title>Rotational Spectrum of CBr by Kinetic Microwave Spectroscopy of 193-nm Photolysis Products of Bromoform</title><title>Journal of molecular spectroscopy</title><addtitle>J Mol Spectrosc</addtitle><description>We have measured the first millimeter-wave spectrum of CBr. The radical was produced by pulsed UV–laser photolysis of bromoform at 193 nm and detected using kinetic spectroscopy. We have significantly improved the rotational and fine structure constants for the ground vibrational state. The hyperfine structure due to the bromine nucleus has been resolved and quadrupole and magnetic hyperfine parameters evaluated for the first time.</description><subject>bromoform</subject><subject>CBr</subject><subject>excimer laser</subject><subject>kinetic</subject><subject>microwave</subject><subject>photolysis</subject><subject>rotational spectra</subject><issn>0022-2852</issn><issn>1096-083X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><recordid>eNp1kDtPwzAUhS0EouWxMqKMLCl-xIk9QsVLgKh4SGyW61yDURIHOynqvydRO7Aw3eF-50jnQ-iE4BnBOD__qmM7I1LKmcAM76ApwTJPsWDvu2iKMaUpFZxO0EGMXxgTwgu2jyYE5znlBZ2ij2ff6c75RlfJSwumC32deJvML0OyXCf3roHOmeTRmeB_9Aq2kI_Gt-sRJJKlTZ0sPn3nq3V0MVkEX_ami-P3MvjaWx_qI7RndRXheHsP0dv11ev8Nn14urmbXzykhmW0S2mecU1hCTzDkolcQAYZF9ZgW1BCbQYGLORlZnKgQuoCUylJSbRcFkRbzg7R2aa3Df67h9ip2kUDVaUb8H1URHDJSMY5G9DZBh2mxRjAqja4Woe1IliNctUoV41y1Sh3CJxuu_tlDeUffGNzAMQGgGHhykFQ0ThoDJQuDNZU6d1_3b8pBIls</recordid><startdate>20000301</startdate><enddate>20000301</enddate><creator>Hassouna, M.</creator><creator>Walters, A.</creator><creator>Demuynck, C.</creator><creator>Bogey, M.</creator><general>Elsevier Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20000301</creationdate><title>Rotational Spectrum of CBr by Kinetic Microwave Spectroscopy of 193-nm Photolysis Products of Bromoform</title><author>Hassouna, M. ; Walters, A. ; Demuynck, C. ; Bogey, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c342t-2645a2ebe54093868e4e458fc0f7212f4ecefe6d4c6e289a702991d1a9b71af53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2000</creationdate><topic>bromoform</topic><topic>CBr</topic><topic>excimer laser</topic><topic>kinetic</topic><topic>microwave</topic><topic>photolysis</topic><topic>rotational spectra</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hassouna, M.</creatorcontrib><creatorcontrib>Walters, A.</creatorcontrib><creatorcontrib>Demuynck, C.</creatorcontrib><creatorcontrib>Bogey, M.</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of molecular spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hassouna, M.</au><au>Walters, A.</au><au>Demuynck, C.</au><au>Bogey, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rotational Spectrum of CBr by Kinetic Microwave Spectroscopy of 193-nm Photolysis Products of Bromoform</atitle><jtitle>Journal of molecular spectroscopy</jtitle><addtitle>J Mol Spectrosc</addtitle><date>2000-03-01</date><risdate>2000</risdate><volume>200</volume><issue>1</issue><spage>16</spage><epage>24</epage><pages>16-24</pages><issn>0022-2852</issn><eissn>1096-083X</eissn><abstract>We have measured the first millimeter-wave spectrum of CBr. The radical was produced by pulsed UV–laser photolysis of bromoform at 193 nm and detected using kinetic spectroscopy. We have significantly improved the rotational and fine structure constants for the ground vibrational state. The hyperfine structure due to the bromine nucleus has been resolved and quadrupole and magnetic hyperfine parameters evaluated for the first time.</abstract><cop>United States</cop><pub>Elsevier Inc</pub><pmid>10662572</pmid><doi>10.1006/jmsp.1999.8030</doi><tpages>9</tpages></addata></record>
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subjects	bromoform CBr excimer laser kinetic microwave photolysis rotational spectra
title	Rotational Spectrum of CBr by Kinetic Microwave Spectroscopy of 193-nm Photolysis Products of Bromoform
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