Evidence for an Equilibrium between an N-heterocyclic Carbene and Its Dimer in Solution
Evidence for the Wanzlick equilibrium between carbene 1 and dibenzotetraazafulvalene (1)2 at ambient temperature has been found (see scheme). Enetetramines of type (1)2 can also be cleaved by coordinatively unsaturated transition metal compounds to form dicarbene complexes.
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| Veröffentlicht in: | Angewandte Chemie International Edition 2000-02, Vol.39 (3), p.541-544 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Hahn, F. Ekkehardt Wittenbecher, Lars Le Van, Duc Fröhlich, Roland |
| description | Evidence for the Wanzlick equilibrium between carbene 1 and dibenzotetraazafulvalene (1)2 at ambient temperature has been found (see scheme). Enetetramines of type (1)2 can also be cleaved by coordinatively unsaturated transition metal compounds to form dicarbene complexes. |
| doi_str_mv | 10.1002/(SICI)1521-3773(20000204)39:3<541::AID-ANIE541>3.0.CO;2-B |
| format | Article |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | carbene complexes carbenes equilibrium structure elucidation |
| title | Evidence for an Equilibrium between an N-heterocyclic Carbene and Its Dimer in Solution |
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