Epitaxial Electrodeposition of Lead Sulfide on (100)-Oriented Single-Crystal Gold

Small lattice mismatches and gas‐phase deposition are typically used for growing epitaxial films on single‐crystal substrates. A 1‐μm thick film of PbS can be epitaxially electrodeposited onto a Au (100) single crystal. The large lattice mismatch (45.5 %) between Au and PbS is accommodated by the fo...

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Veröffentlicht in:Angewandte Chemie International Edition 1999-11, Vol.38 (21), p.3169-3171
Hauptverfasser: Vertegel, Alexey A., Shumsky, Mark G., Switzer, Jay A.
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container_title Angewandte Chemie International Edition
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creator Vertegel, Alexey A.
Shumsky, Mark G.
Switzer, Jay A.
description Small lattice mismatches and gas‐phase deposition are typically used for growing epitaxial films on single‐crystal substrates. A 1‐μm thick film of PbS can be epitaxially electrodeposited onto a Au (100) single crystal. The large lattice mismatch (45.5 %) between Au and PbS is accommodated by the formation of a coincidence lattice, in which the epitaxial film is rotated by 45° relative to the substrate. The coincidence lattice reduces the mismatch to +2.9 %.
doi_str_mv 10.1002/(SICI)1521-3773(19991102)38:21<3169::AID-ANIE3169>3.0.CO;2-0
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subjects Deposition
Electrochemistry
Electrodeposition
Epitaxial growth
Epitaxy
Formations
Gold
Lattices
Lead sulfide
Semiconductors
Single crystals
Surface chemistry
Thick films
title Epitaxial Electrodeposition of Lead Sulfide on (100)-Oriented Single-Crystal Gold
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