Towards Sixfold Functionalization of Buckminsterfullerene (C60) at Fully Addressable Octahedral Sites

Selective C60‐functionalizations that provide access to unusual multifunctional molecules are of interest in the construction of highly organized three‐dimensional assemblies. The temporary “masking” of three of the most reactive sites on C60 by a bisdiene tether has allowed the facile and high‐yiel...

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Veröffentlicht in:Angewandte Chemie International Edition 1999-08, Vol.38 (16), p.2356-2360
Hauptverfasser: Qian, Wenyuan, Rubin, Yves
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Rubin, Yves
description Selective C60‐functionalizations that provide access to unusual multifunctional molecules are of interest in the construction of highly organized three‐dimensional assemblies. The temporary “masking” of three of the most reactive sites on C60 by a bisdiene tether has allowed the facile and high‐yielding formation of the fully differentiated trisadduct 1 and the interesting hexaadduct 2.
doi_str_mv 10.1002/(SICI)1521-3773(19990816)38:16<2356::AID-ANIE2356>3.0.CO;2-Y
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source Wiley Online Library Journals Frontfile Complete
subjects Assemblies
Buckminsterfullerene
Construction
Cycloadditions
Diels-Alder reactions
Diimines
Formations
Fullerenes
Masking
Semiempirical calculations
Tethers
Three dimensional
title Towards Sixfold Functionalization of Buckminsterfullerene (C60) at Fully Addressable Octahedral Sites
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