Towards Sixfold Functionalization of Buckminsterfullerene (C60) at Fully Addressable Octahedral Sites
Selective C60‐functionalizations that provide access to unusual multifunctional molecules are of interest in the construction of highly organized three‐dimensional assemblies. The temporary “masking” of three of the most reactive sites on C60 by a bisdiene tether has allowed the facile and high‐yiel...
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Veröffentlicht in: | Angewandte Chemie International Edition 1999-08, Vol.38 (16), p.2356-2360 |
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description | Selective C60‐functionalizations that provide access to unusual multifunctional molecules are of interest in the construction of highly organized three‐dimensional assemblies. The temporary “masking” of three of the most reactive sites on C60 by a bisdiene tether has allowed the facile and high‐yielding formation of the fully differentiated trisadduct 1 and the interesting hexaadduct 2. |
doi_str_mv | 10.1002/(SICI)1521-3773(19990816)38:16<2356::AID-ANIE2356>3.0.CO;2-Y |
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source | Wiley Online Library Journals Frontfile Complete |
subjects | Assemblies Buckminsterfullerene Construction Cycloadditions Diels-Alder reactions Diimines Formations Fullerenes Masking Semiempirical calculations Tethers Three dimensional |
title | Towards Sixfold Functionalization of Buckminsterfullerene (C60) at Fully Addressable Octahedral Sites |
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