Chemical and Structural Properties of Jordanian Zeolitic Tuffs and Their Admixtures with Urea and Thiourea: Potential Scavengers for Phenolics in Aqueous Medium
Native Jordanian zeolitic tuffs, rich in phillipsite, were treated with urea and thiourea. The chemical and structural properties of the tuffs and their urea and thiourea admixtures were studied using SEM, XRF, XRD, and FTIR techniques, and their adsorption capacities were estimated by the methylene...
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| Veröffentlicht in: | Journal of Colloid and Interface Science 1999-08, Vol.216 (2), p.348-359 |
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| creator | Yousef, Rushdi I Tutunji, Maha F Derwish, Ghazi A.W Musleh, Salem M |
| description | Native Jordanian zeolitic tuffs, rich in phillipsite, were treated with urea and thiourea. The chemical and structural properties of the tuffs and their urea and thiourea admixtures were studied using SEM, XRF, XRD, and FTIR techniques, and their adsorption capacities were estimated by the methylene blue method. The urea and thiourea treatment has not affected the mineral constitution of the tuffs. The results revealed that urea and thiourea were linked by hydrogen bonding through the NH2 moiety to the zeolite substrate, with urea showing the strongest effect. Experiments were carried out to investigate the possible use of the prepared materials for the removal of phenol and chlorinated phenols from aqueous solutions. Although thiourea caused a reduction in the relative surface area, both urea and thiourea admixtures were more effective than the free zeolitic tuff in the removal of phenol and chlorinated phenols from water, with urea admixture displaying the largest removal capacity. |
| doi_str_mv | 10.1006/jcis.1999.6334 |
| format | Article |
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The chemical and structural properties of the tuffs and their urea and thiourea admixtures were studied using SEM, XRF, XRD, and FTIR techniques, and their adsorption capacities were estimated by the methylene blue method. The urea and thiourea treatment has not affected the mineral constitution of the tuffs. The results revealed that urea and thiourea were linked by hydrogen bonding through the NH2 moiety to the zeolite substrate, with urea showing the strongest effect. Experiments were carried out to investigate the possible use of the prepared materials for the removal of phenol and chlorinated phenols from aqueous solutions. Although thiourea caused a reduction in the relative surface area, both urea and thiourea admixtures were more effective than the free zeolitic tuff in the removal of phenol and chlorinated phenols from water, with urea admixture displaying the largest removal capacity.</description><identifier>ISSN: 0021-9797</identifier><identifier>EISSN: 1095-7103</identifier><identifier>DOI: 10.1006/jcis.1999.6334</identifier><identifier>PMID: 10421742</identifier><identifier>CODEN: JCISA5</identifier><language>eng</language><publisher>San Diego, CA: Elsevier Inc</publisher><subject>ADSORPTION ; CHEMICAL PROPERTIES ; Chemistry ; CHLORINATED AROMATIC HYDROCARBONS ; ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION ; ENVIRONMENTAL SCIENCES ; Exact sciences and technology ; General and physical chemistry ; JORDAN ; PHENOLS ; Solid-liquid interface ; SORPTIVE PROPERTIES ; Surface physical chemistry ; thiourea ; TUFF ; urea ; WASTE WATER ; WATER TREATMENT ; zeolitic tuff</subject><ispartof>Journal of Colloid and Interface Science, 1999-08, Vol.216 (2), p.348-359</ispartof><rights>1999 Academic Press</rights><rights>1999 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c397t-7929defbdbae3f262e7e92f82f19e35cf813ed56ddc286f0f739626302fdb5ea3</citedby><cites>FETCH-LOGICAL-c397t-7929defbdbae3f262e7e92f82f19e35cf813ed56ddc286f0f739626302fdb5ea3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1006/jcis.1999.6334$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,885,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=1908022$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/10421742$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/680111$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Yousef, Rushdi I</creatorcontrib><creatorcontrib>Tutunji, Maha F</creatorcontrib><creatorcontrib>Derwish, Ghazi A.W</creatorcontrib><creatorcontrib>Musleh, Salem M</creatorcontrib><title>Chemical and Structural Properties of Jordanian Zeolitic Tuffs and Their Admixtures with Urea and Thiourea: Potential Scavengers for Phenolics in Aqueous Medium</title><title>Journal of Colloid and Interface Science</title><addtitle>J Colloid Interface Sci</addtitle><description>Native Jordanian zeolitic tuffs, rich in phillipsite, were treated with urea and thiourea. The chemical and structural properties of the tuffs and their urea and thiourea admixtures were studied using SEM, XRF, XRD, and FTIR techniques, and their adsorption capacities were estimated by the methylene blue method. The urea and thiourea treatment has not affected the mineral constitution of the tuffs. The results revealed that urea and thiourea were linked by hydrogen bonding through the NH2 moiety to the zeolite substrate, with urea showing the strongest effect. Experiments were carried out to investigate the possible use of the prepared materials for the removal of phenol and chlorinated phenols from aqueous solutions. 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The chemical and structural properties of the tuffs and their urea and thiourea admixtures were studied using SEM, XRF, XRD, and FTIR techniques, and their adsorption capacities were estimated by the methylene blue method. The urea and thiourea treatment has not affected the mineral constitution of the tuffs. The results revealed that urea and thiourea were linked by hydrogen bonding through the NH2 moiety to the zeolite substrate, with urea showing the strongest effect. Experiments were carried out to investigate the possible use of the prepared materials for the removal of phenol and chlorinated phenols from aqueous solutions. Although thiourea caused a reduction in the relative surface area, both urea and thiourea admixtures were more effective than the free zeolitic tuff in the removal of phenol and chlorinated phenols from water, with urea admixture displaying the largest removal capacity.</abstract><cop>San Diego, CA</cop><pub>Elsevier Inc</pub><pmid>10421742</pmid><doi>10.1006/jcis.1999.6334</doi><tpages>12</tpages></addata></record> |
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| ispartof | Journal of Colloid and Interface Science, 1999-08, Vol.216 (2), p.348-359 |
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| subjects | ADSORPTION CHEMICAL PROPERTIES Chemistry CHLORINATED AROMATIC HYDROCARBONS ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION ENVIRONMENTAL SCIENCES Exact sciences and technology General and physical chemistry JORDAN PHENOLS Solid-liquid interface SORPTIVE PROPERTIES Surface physical chemistry thiourea TUFF urea WASTE WATER WATER TREATMENT zeolitic tuff |
| title | Chemical and Structural Properties of Jordanian Zeolitic Tuffs and Their Admixtures with Urea and Thiourea: Potential Scavengers for Phenolics in Aqueous Medium |
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