Acid–Base Approach to Latex Particles Containing Specific Groups Based on Wettability Measurements

Polar properties of latex particles containing specific groups with various surface charge densities were examined from contact angle measurements using “old” polar/dispersive models. It was determined that the Fowkes approach is quite sufficient for classifying our functionalized polystyrene latice...

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Veröffentlicht in:Journal of colloid and interface science 1998-12, Vol.208 (1), p.81-89
Hauptverfasser: Bouali, Bachir, Ganachaud, François, Chapel, Jean-Paul, Pichot, Christan, Lanteri, Pierre
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container_issue 1
container_start_page 81
container_title Journal of colloid and interface science
container_volume 208
creator Bouali, Bachir
Ganachaud, François
Chapel, Jean-Paul
Pichot, Christan
Lanteri, Pierre
description Polar properties of latex particles containing specific groups with various surface charge densities were examined from contact angle measurements using “old” polar/dispersive models. It was determined that the Fowkes approach is quite sufficient for classifying our functionalized polystyrene latices. The pertinence to our systems of the acid–base approach, which has a more pronounced chemical background, was then investigated, and the strong dependence of the acid–base parameters (γ⊕, γΘ) on the acid–base scale chosen for the reference liquid (water) was shown. Finally, using the receding angle values revealed the outermost surface buried moieties in the latex particles, which were not seen in the advancing angle measurements.
doi_str_mv 10.1006/jcis.1998.5775
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subjects acid–base approach
Applied sciences
contact angle
Exact sciences and technology
functionalized polystyrene latices
Organic polymers
Physicochemistry of polymers
polarity
Properties and characterization
surface free energy
Surface properties
title Acid–Base Approach to Latex Particles Containing Specific Groups Based on Wettability Measurements
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