Mixtures of Ascorbyl-stearate and Vitamin D3: A Monolayer Study at the Gas/Water Interface

Vitamin C and vitamin D3perform different and important activities in living systems. Vitamin D3forms stable monomolecular films at the gas/water interface and, at higher concentrations, produces large aggregates in water solutions. Because of their amphiphilic structure, vitamin C alkyl esters form...

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Veröffentlicht in:Journal of colloid and interface science 1997-02, Vol.186 (2), p.271-279
Hauptverfasser: Capuzzi, Giulia, Kulkarni, Kavita, Fernandez, Jack E., Vincieri, Franco F., Lo Nostro, Pierandrea
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container_end_page 279
container_issue 2
container_start_page 271
container_title Journal of colloid and interface science
container_volume 186
creator Capuzzi, Giulia
Kulkarni, Kavita
Fernandez, Jack E.
Vincieri, Franco F.
Lo Nostro, Pierandrea
description Vitamin C and vitamin D3perform different and important activities in living systems. Vitamin D3forms stable monomolecular films at the gas/water interface and, at higher concentrations, produces large aggregates in water solutions. Because of their amphiphilic structure, vitamin C alkyl esters form monolayers, micelles, vesicles, or microemulsions in water, depending on composition, concentration, solvent, and temperature. In this work the monolayer of 6-O-ascorbyl-stearate and vitamin D3was studied to investigate the behavior of the two compounds and their mixtures at the gas/water interface at different temperatures, at different pH, and in the presence of Ca2+in the subphase. The results show that stable Langmuir films are formed in all molar ratios, with repulsive interactions between the two components, and that the presence of calcium ions modifies the properties of the monolayer.
doi_str_mv 10.1006/jcis.1996.4646
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Psychology</topic><topic>miscibility</topic><topic>mixed monolayer(s)</topic><topic>Molecular biophysics</topic><topic>Other biological molecules</topic><topic>spreading monolayer(s)</topic><topic>Surface properties. 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source Elsevier ScienceDirect Journals
subjects Analytical, structural and metabolic biochemistry
ascorbyl-6-O-stearate
Biological and medical sciences
Coenzymes, vitamins
Fundamental and applied biological sciences. Psychology
miscibility
mixed monolayer(s)
Molecular biophysics
Other biological molecules
spreading monolayer(s)
Surface properties. Adsorption
vitamin C
vitamin D3
title Mixtures of Ascorbyl-stearate and Vitamin D3: A Monolayer Study at the Gas/Water Interface
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