Metal–Organic Cooperative Catalysis in C–H and C–C Bond Activation
Transition-metal-catalyzed activation of C–H and C–C bonds is a challenging area in synthetic organic chemistry. Among various methods to accomplish these processes, the approach using metal–organic cooperative catalytic systems is one of the most promising. In this protocol, organic molecules as we...
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| Veröffentlicht in: | Chemical reviews 2017-07, Vol.117 (13), p.8977-9015 |
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| container_title | Chemical reviews |
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| creator | Kim, Dong-Su Park, Woo-Jin Jun, Chul-Ho |
| description | Transition-metal-catalyzed activation of C–H and C–C bonds is a challenging area in synthetic organic chemistry. Among various methods to accomplish these processes, the approach using metal–organic cooperative catalytic systems is one of the most promising. In this protocol, organic molecules as well as transition metals act as catalysts to bring about reactions, which proceed with high efficiencies and selectivities. Various metal–organic cooperative catalytic systems developed for C–H and C–C bond activation reactions are discussed in this review. Also discussed are how each metal–organic cooperative catalyst affects the reaction mechanism and what kinds of substrates can be applied in each of the catalytic processes. |
| doi_str_mv | 10.1021/acs.chemrev.6b00554 |
| format | Article |
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Also discussed are how each metal–organic cooperative catalyst affects the reaction mechanism and what kinds of substrates can be applied in each of the catalytic processes.</description><identifier>ISSN: 0009-2665</identifier><identifier>EISSN: 1520-6890</identifier><identifier>DOI: 10.1021/acs.chemrev.6b00554</identifier><identifier>PMID: 28060495</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>Activation ; Carbon ; Catalysis ; Catalysts ; Chemical bonds ; Chemical reactions ; Hydrogen bonds ; Metals ; Molecules ; Organic chemistry ; Reaction mechanisms ; Substrates ; Transition metals</subject><ispartof>Chemical reviews, 2017-07, Vol.117 (13), p.8977-9015</ispartof><rights>Copyright © 2017 American Chemical Society</rights><rights>Copyright American Chemical Society Jul 12, 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a439t-6f7c2c4015c072929bcb4060c2ec3afc3d5013f3d5d01592ed005b92f5728c653</citedby><cites>FETCH-LOGICAL-a439t-6f7c2c4015c072929bcb4060c2ec3afc3d5013f3d5d01592ed005b92f5728c653</cites><orcidid>0000-0002-5578-2228</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.chemrev.6b00554$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.chemrev.6b00554$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28060495$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kim, Dong-Su</creatorcontrib><creatorcontrib>Park, Woo-Jin</creatorcontrib><creatorcontrib>Jun, Chul-Ho</creatorcontrib><title>Metal–Organic Cooperative Catalysis in C–H and C–C Bond Activation</title><title>Chemical reviews</title><addtitle>Chem. 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Also discussed are how each metal–organic cooperative catalyst affects the reaction mechanism and what kinds of substrates can be applied in each of the catalytic processes.</description><subject>Activation</subject><subject>Carbon</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical bonds</subject><subject>Chemical reactions</subject><subject>Hydrogen bonds</subject><subject>Metals</subject><subject>Molecules</subject><subject>Organic chemistry</subject><subject>Reaction mechanisms</subject><subject>Substrates</subject><subject>Transition metals</subject><issn>0009-2665</issn><issn>1520-6890</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp9kEFOwzAQRS0EoqVwAiQUiQ2btGMndupliYAiFXUDa8txHEiVxMVOKnXHHbghJ8GlASQWrGakef_P10foHMMYA8ETqdxYveja6s2YZQCUxgdoiCmBkE05HKIhAPCQMEYH6MS5FewYkhyjAZkCg5jTIZo_6FZWH2_vS_ssm1IFqTFrbWVbbnSQSn_butIFZROkHpoHssm_tjS4Nn6dKQ962DSn6KiQldNn_Ryhp9ubx3QeLpZ39-lsEco44m3IikQRFQOmChLCCc9UFvswimgVyUJFOQUcFX7knuFE5z50xklBEzJVjEYjdLX3XVvz2mnXirp0SleVbLTpnMBTyigHmjCPXv5BV6azjU8nMGc4JlEM3FPRnlLWOGd1Ida2rKXdCgxiV7TwRYu-aNEX7VUXvXeX1Tr_0Xw364HJHtipf__-Y_kJtDaMYQ</recordid><startdate>20170712</startdate><enddate>20170712</enddate><creator>Kim, Dong-Su</creator><creator>Park, Woo-Jin</creator><creator>Jun, Chul-Ho</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-5578-2228</orcidid></search><sort><creationdate>20170712</creationdate><title>Metal–Organic Cooperative Catalysis in C–H and C–C Bond Activation</title><author>Kim, Dong-Su ; Park, Woo-Jin ; Jun, Chul-Ho</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a439t-6f7c2c4015c072929bcb4060c2ec3afc3d5013f3d5d01592ed005b92f5728c653</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Activation</topic><topic>Carbon</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemical bonds</topic><topic>Chemical reactions</topic><topic>Hydrogen bonds</topic><topic>Metals</topic><topic>Molecules</topic><topic>Organic chemistry</topic><topic>Reaction mechanisms</topic><topic>Substrates</topic><topic>Transition metals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kim, Dong-Su</creatorcontrib><creatorcontrib>Park, Woo-Jin</creatorcontrib><creatorcontrib>Jun, Chul-Ho</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical reviews</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kim, Dong-Su</au><au>Park, Woo-Jin</au><au>Jun, Chul-Ho</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Metal–Organic Cooperative Catalysis in C–H and C–C Bond Activation</atitle><jtitle>Chemical reviews</jtitle><addtitle>Chem. 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| ispartof | Chemical reviews, 2017-07, Vol.117 (13), p.8977-9015 |
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| language | eng |
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| source | American Chemical Society Journals |
| subjects | Activation Carbon Catalysis Catalysts Chemical bonds Chemical reactions Hydrogen bonds Metals Molecules Organic chemistry Reaction mechanisms Substrates Transition metals |
| title | Metal–Organic Cooperative Catalysis in C–H and C–C Bond Activation |
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