Metal-organic framework nanosheets for fast-response and highly sensitive luminescent sensing of Fe3

The first luminescent two-dimensional MOF nanosheets NTU-9-NS Ti2(HDOBDC)2(H2DOBDC) (H2DOBDC = 2,5-dihydroxyterephthalic acid) fabricated via top-down delamination have been realized for the highly sensitive sensing of Fe3+ with a fast response. The highly dispersive nature and highly accessible act...

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Veröffentlicht in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2016-07, Vol.4 (28), p.10900-10905
Hauptverfasser: Xu, Hui, Gao, Junkuo, Qian, Xuefeng, Wang, Jiangpeng, He, Huajun, Cui, Yuanjing, Yang, Yu, Wang, Zhiyu, Qian, Guodong
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container_end_page 10905
container_issue 28
container_start_page 10900
container_title Journal of materials chemistry. A, Materials for energy and sustainability
container_volume 4
creator Xu, Hui
Gao, Junkuo
Qian, Xuefeng
Wang, Jiangpeng
He, Huajun
Cui, Yuanjing
Yang, Yu
Wang, Zhiyu
Qian, Guodong
description The first luminescent two-dimensional MOF nanosheets NTU-9-NS Ti2(HDOBDC)2(H2DOBDC) (H2DOBDC = 2,5-dihydroxyterephthalic acid) fabricated via top-down delamination have been realized for the highly sensitive sensing of Fe3+ with a fast response. The highly dispersive nature and highly accessible active sites on the surface of the 2D NTU-9-NS nanosheets enable them to have close contact with targeted metal ions, which leads to the highly sensitive sensing of Fe3+ ions, with a fast response time within seconds and the best detection limit performance of 0.45 mu M among MOF materials. The fast response and highly sensitive Fe3+ sensing based on the NTU-9-NS nanosheets sensor material highlights the promise of the two-dimensional MOF nanosheet approach for luminescent sensing applications. This work contributes to the development of research on two-dimensional MOF nanosheets materials with targeted and specific recognition for the application of biological and environmental luminescent sensors.
doi_str_mv 10.1039/c6ta03065c
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Accessibility
Contact
Detection
Lead (metal)
Nanostructure
Recognition
Sensors
Surface chemistry
title Metal-organic framework nanosheets for fast-response and highly sensitive luminescent sensing of Fe3
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