Synthesis of Cycloparaphenylenes Bearing Furan-2,5-diyl or 2,2'-Bifuran-5,5'-diyl Units in the Macrocyclic Structures
Synthetic pathways to furan‐containing cycloparaphenylenes (CPPs) as molecular nanohoops bearing 10, 12, and 15 aromatic units including furan‐2,5‐diyl or 2,2’‐bifuran‐5,5’‐diyl units have been developed. The X‐ray structures of a partially hydrogenated bifuran‐containing CPP precursor and the corre...
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Veröffentlicht in: | Chemistry : a European journal 2016-11, Vol.22 (46), p.16420-16424 |
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creator | Farajidizaji, Behzad Thakellapalli, Haresh Li, Shuangjiang Huang, Changfeng Baughman, Notashia N. Akhmedov, Novruz G. Popp, Brian V. Petersen, Jeffrey L. Wang, Kung K. |
description | Synthetic pathways to furan‐containing cycloparaphenylenes (CPPs) as molecular nanohoops bearing 10, 12, and 15 aromatic units including furan‐2,5‐diyl or 2,2’‐bifuran‐5,5’‐diyl units have been developed. The X‐ray structures of a partially hydrogenated bifuran‐containing CPP precursor and the corresponding fully aromatized bifuran‐containing CPP were obtained to allow the determination of their conformational arrangements in the crystal lattice. The optical and electrochemical properties of the furan‐containing CPPs were investigated.
Synthetic pathways to furan‐containing cycloparaphenylenes (CPPs) as molecular nanohoops bearing 10, 12, and 15 aromatic units including furan‐2,5‐diyl or 2,2’‐bifuran‐5,5’‐diyl units have been developed. The X‐ray structures of a partially hydrogenated bifuran‐containing CPP precursor and the corresponding fully aromatized bifuran‐containing CPP were obtained. The optical and electrochemical properties of the furan‐containing CPPs were investigated. |
doi_str_mv | 10.1002/chem.201604036 |
format | Article |
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Synthetic pathways to furan‐containing cycloparaphenylenes (CPPs) as molecular nanohoops bearing 10, 12, and 15 aromatic units including furan‐2,5‐diyl or 2,2’‐bifuran‐5,5’‐diyl units have been developed. The X‐ray structures of a partially hydrogenated bifuran‐containing CPP precursor and the corresponding fully aromatized bifuran‐containing CPP were obtained. The optical and electrochemical properties of the furan‐containing CPPs were investigated.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201604036</identifier><identifier>PMID: 27607838</identifier><identifier>CODEN: CEUJED</identifier><language>eng</language><publisher>Germany: Blackwell Publishing Ltd</publisher><subject>Bearing ; Chemistry ; cross-coupling ; Crystal lattices ; cycloaddition ; cycloparaphenylenes ; Electrochemical analysis ; Electrochemistry ; furans ; Macrocyclic compounds ; Molecular structure ; Nanostructure ; Optical properties ; oxidative aromatization ; Pathways ; Precursors ; X-rays</subject><ispartof>Chemistry : a European journal, 2016-11, Vol.22 (46), p.16420-16424</ispartof><rights>2016 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5606-b7b56626733cd9264d3f3018b5fd0787a63fe623b0d395e44278ef18ce2be6913</citedby><cites>FETCH-LOGICAL-c5606-b7b56626733cd9264d3f3018b5fd0787a63fe623b0d395e44278ef18ce2be6913</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201604036$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201604036$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27607838$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Farajidizaji, Behzad</creatorcontrib><creatorcontrib>Thakellapalli, Haresh</creatorcontrib><creatorcontrib>Li, Shuangjiang</creatorcontrib><creatorcontrib>Huang, Changfeng</creatorcontrib><creatorcontrib>Baughman, Notashia N.</creatorcontrib><creatorcontrib>Akhmedov, Novruz G.</creatorcontrib><creatorcontrib>Popp, Brian V.</creatorcontrib><creatorcontrib>Petersen, Jeffrey L.</creatorcontrib><creatorcontrib>Wang, Kung K.</creatorcontrib><title>Synthesis of Cycloparaphenylenes Bearing Furan-2,5-diyl or 2,2'-Bifuran-5,5'-diyl Units in the Macrocyclic Structures</title><title>Chemistry : a European journal</title><addtitle>Chem. Eur. J</addtitle><description>Synthetic pathways to furan‐containing cycloparaphenylenes (CPPs) as molecular nanohoops bearing 10, 12, and 15 aromatic units including furan‐2,5‐diyl or 2,2’‐bifuran‐5,5’‐diyl units have been developed. The X‐ray structures of a partially hydrogenated bifuran‐containing CPP precursor and the corresponding fully aromatized bifuran‐containing CPP were obtained to allow the determination of their conformational arrangements in the crystal lattice. The optical and electrochemical properties of the furan‐containing CPPs were investigated.
Synthetic pathways to furan‐containing cycloparaphenylenes (CPPs) as molecular nanohoops bearing 10, 12, and 15 aromatic units including furan‐2,5‐diyl or 2,2’‐bifuran‐5,5’‐diyl units have been developed. The X‐ray structures of a partially hydrogenated bifuran‐containing CPP precursor and the corresponding fully aromatized bifuran‐containing CPP were obtained. The optical and electrochemical properties of the furan‐containing CPPs were investigated.</description><subject>Bearing</subject><subject>Chemistry</subject><subject>cross-coupling</subject><subject>Crystal lattices</subject><subject>cycloaddition</subject><subject>cycloparaphenylenes</subject><subject>Electrochemical analysis</subject><subject>Electrochemistry</subject><subject>furans</subject><subject>Macrocyclic compounds</subject><subject>Molecular structure</subject><subject>Nanostructure</subject><subject>Optical properties</subject><subject>oxidative aromatization</subject><subject>Pathways</subject><subject>Precursors</subject><subject>X-rays</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqNkc9v0zAYhi0EYmVw5YgicRiHptj-_CM-btG2Iq1wGGNHy3Ec6pEmxU7E8t_PpaNCHICTD9_zPvr8vQi9JnhBMKbv7dptFhQTgRkG8QTNCKckByn4UzTDislccFBH6EWMdxhjJQCeoyMqBZYFFDM0Xk_dsHbRx6xvsnKybb81wWzXrpta17mYnTkTfPc1uxiD6XI653ntpzbrQ0bn9CQ_883PAZ_zk_3kpvNDzHyXJW-2Mjb0Nmm9za6HMNphDC6-RM8a00b36vE9RjcX55_LZX716fJDeXqVWy6wyCtZcSGokAC2VlSwGhrApKh4U6f9pRHQOEGhwjUo7hijsnANKayjlROKwDF6t_duQ_99dHHQGx-ta1vTuX6MmhQ8XYcxLv8DBQ5cKV4k9O0f6F0_hi59RBOFJRAQgv2VKoClhjDbbbjYU-lMMQbX6G3wGxMmTbDeNax3DetDwynw5lE7VhtXH_BflSZA7YEfvnXTP3S6XJ6vfpfn-6yPg7s_ZE34plMJkuvbj5d6tbwlX0olNYcHUzq9oQ</recordid><startdate>20161107</startdate><enddate>20161107</enddate><creator>Farajidizaji, Behzad</creator><creator>Thakellapalli, Haresh</creator><creator>Li, Shuangjiang</creator><creator>Huang, Changfeng</creator><creator>Baughman, Notashia N.</creator><creator>Akhmedov, Novruz G.</creator><creator>Popp, Brian V.</creator><creator>Petersen, Jeffrey L.</creator><creator>Wang, Kung K.</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20161107</creationdate><title>Synthesis of Cycloparaphenylenes Bearing Furan-2,5-diyl or 2,2'-Bifuran-5,5'-diyl Units in the Macrocyclic Structures</title><author>Farajidizaji, Behzad ; Thakellapalli, Haresh ; Li, Shuangjiang ; Huang, Changfeng ; Baughman, Notashia N. ; Akhmedov, Novruz G. ; Popp, Brian V. ; Petersen, Jeffrey L. ; Wang, Kung K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5606-b7b56626733cd9264d3f3018b5fd0787a63fe623b0d395e44278ef18ce2be6913</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Bearing</topic><topic>Chemistry</topic><topic>cross-coupling</topic><topic>Crystal lattices</topic><topic>cycloaddition</topic><topic>cycloparaphenylenes</topic><topic>Electrochemical analysis</topic><topic>Electrochemistry</topic><topic>furans</topic><topic>Macrocyclic compounds</topic><topic>Molecular structure</topic><topic>Nanostructure</topic><topic>Optical properties</topic><topic>oxidative aromatization</topic><topic>Pathways</topic><topic>Precursors</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Farajidizaji, Behzad</creatorcontrib><creatorcontrib>Thakellapalli, Haresh</creatorcontrib><creatorcontrib>Li, Shuangjiang</creatorcontrib><creatorcontrib>Huang, Changfeng</creatorcontrib><creatorcontrib>Baughman, Notashia N.</creatorcontrib><creatorcontrib>Akhmedov, Novruz G.</creatorcontrib><creatorcontrib>Popp, Brian V.</creatorcontrib><creatorcontrib>Petersen, Jeffrey L.</creatorcontrib><creatorcontrib>Wang, Kung K.</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Farajidizaji, Behzad</au><au>Thakellapalli, Haresh</au><au>Li, Shuangjiang</au><au>Huang, Changfeng</au><au>Baughman, Notashia N.</au><au>Akhmedov, Novruz G.</au><au>Popp, Brian V.</au><au>Petersen, Jeffrey L.</au><au>Wang, Kung K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Cycloparaphenylenes Bearing Furan-2,5-diyl or 2,2'-Bifuran-5,5'-diyl Units in the Macrocyclic Structures</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chem. Eur. J</addtitle><date>2016-11-07</date><risdate>2016</risdate><volume>22</volume><issue>46</issue><spage>16420</spage><epage>16424</epage><pages>16420-16424</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><coden>CEUJED</coden><abstract>Synthetic pathways to furan‐containing cycloparaphenylenes (CPPs) as molecular nanohoops bearing 10, 12, and 15 aromatic units including furan‐2,5‐diyl or 2,2’‐bifuran‐5,5’‐diyl units have been developed. The X‐ray structures of a partially hydrogenated bifuran‐containing CPP precursor and the corresponding fully aromatized bifuran‐containing CPP were obtained to allow the determination of their conformational arrangements in the crystal lattice. The optical and electrochemical properties of the furan‐containing CPPs were investigated.
Synthetic pathways to furan‐containing cycloparaphenylenes (CPPs) as molecular nanohoops bearing 10, 12, and 15 aromatic units including furan‐2,5‐diyl or 2,2’‐bifuran‐5,5’‐diyl units have been developed. The X‐ray structures of a partially hydrogenated bifuran‐containing CPP precursor and the corresponding fully aromatized bifuran‐containing CPP were obtained. The optical and electrochemical properties of the furan‐containing CPPs were investigated.</abstract><cop>Germany</cop><pub>Blackwell Publishing Ltd</pub><pmid>27607838</pmid><doi>10.1002/chem.201604036</doi><tpages>5</tpages></addata></record> |
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subjects | Bearing Chemistry cross-coupling Crystal lattices cycloaddition cycloparaphenylenes Electrochemical analysis Electrochemistry furans Macrocyclic compounds Molecular structure Nanostructure Optical properties oxidative aromatization Pathways Precursors X-rays |
title | Synthesis of Cycloparaphenylenes Bearing Furan-2,5-diyl or 2,2'-Bifuran-5,5'-diyl Units in the Macrocyclic Structures |
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