Tyrosine-Based Ionic Liquid Crystals: Switching from a Smectic A to a Columnar Mesophase by Exchange of the Spherical Counterion

Synthetic strategies were developed to prepare l‐tyrosine‐based ionic liquid crystals with structural variations at the carboxylic and phenolic OH groups as well as the amino functionality. Salt metathesis additionally led to counterion variation. The liquid‐crystalline properties were investigated...

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Veröffentlicht in:	Chemistry : a European journal 2016-11, Vol.22 (46), p.16494-16504
Hauptverfasser:	Neidhardt, Manuel M., Wolfrum, Manpreet, Beardsworth, Stuart, Wöhrle, Tobias, Frey, Wolfgang, Baro, Angelika, Stubenrauch, Cosima, Giesselmann, Frank, Laschat, Sabine
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetal resins Aggregates amino acids Analogies Bearing Calorimetry Chains Chemistry Chlorides Cross-sections Crystal structure Crystals Curvature Decomposition reactions Differential scanning calorimetry Group theory Heat measurement ionic liquid crystals Ionic liquids Ions Light emitting diodes Liquid crystals Mathematical analysis Mathematical models Mesophase mesophases Microscopy Optical properties Packing Phase transitions Phenolic compounds Phenols Polarization Salts self-assembly Switching Tyrosine X-ray diffraction
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