Synthesis of Benzyltributylstannanes by the Reaction of N‑Tosylhydrazones with Bu3SnH
An efficient stannylation process with N-tosylhydrazones or directly with carbonyl compounds has been developed. A series of functionalized benzyl- and alkyltributylstannanes can be synthesized in moderate to good yields under transition-metal-free conditions. Tandem transformations involving stanny...
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| Veröffentlicht in: | Journal of organic chemistry 2017-01, Vol.82 (1), p.624-632 |
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| container_issue | 1 |
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| container_title | Journal of organic chemistry |
| container_volume | 82 |
| creator | Qiu, Di Wang, Shuai Meng, He Tang, Shengbo Zhang, Yan Wang, Jianbo |
| description | An efficient stannylation process with N-tosylhydrazones or directly with carbonyl compounds has been developed. A series of functionalized benzyl- and alkyltributylstannanes can be synthesized in moderate to good yields under transition-metal-free conditions. Tandem transformations involving stannylation/Stille cross-coupling reaction have been carried out without purification of the benzyltributylstannane intermediates to afford a series of diarylmethane derivatives. |
| doi_str_mv | 10.1021/acs.joc.6b02639 |
| format | Article |
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A series of functionalized benzyl- and alkyltributylstannanes can be synthesized in moderate to good yields under transition-metal-free conditions. 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| ispartof | Journal of organic chemistry, 2017-01, Vol.82 (1), p.624-632 |
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| source | ACS Publications |
| title | Synthesis of Benzyltributylstannanes by the Reaction of N‑Tosylhydrazones with Bu3SnH |
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