A Theoretical Mechanistic Study of the Asymmetric Desymmetrization of a Cyclic meso-Anhydride by a Bifunctional Quinine Sulfonamide Organocatalyst

Cinchona alkaloids and their derivatives are widely used as organocatalysts in asymmetric synthesis. In particular, sulfonamide derivatives of cinchona alkaloids are highly enantioselective desymmetrization catalysts in the ring opening of a variety of cyclic anhydrides. To better understand the mec...

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Veröffentlicht in:	Journal of organic chemistry 2017-02, Vol.82 (3), p.1347-1355
Hauptverfasser:	Blise, Katie, Cvitkovic, Milan W, Gibbs, Nolly J, Roberts, Sean F, Whitaker, Reid M, Hofmeister, Gretchen E, Kohen, Daniela
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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