Development of Electrochemical Oxygen Demand Measurement Cells Using a Diamond Electrode

Development of Electrochemical Oxygen Demand Measurement Cells Using a Diamond Electrode

Electrolytic cells for electrochemical oxygen demand (ECOD) measurements based on total electrolytic decomposition at a boron-doped diamond (BDD) electrode were developed for rapid measurement of organic pollutants at low concentrations. Using improved electrolytic cells designed for efficient mass...

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Veröffentlicht in:Analytical Sciences 2016/12/10, Vol.32(12), pp.1381-1384
Hauptverfasser: KONDO, Takeshi, HOSHINO, Masaki, WATANABE, Takeshi, AIKAWA, Tatsuo, YUASA, Makoto, EINAGA, Yasuaki
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Sprache:eng
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Advancements in Instrumentation
Analytical Chemistry
Boron-doped diamond electrode
Chemistry
electrochemical oxygen demand
organic water pollution
total electrolysis
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container_end_page 1384
container_issue 12
container_start_page 1381
container_title Analytical Sciences
container_volume 32
creator KONDO, Takeshi
HOSHINO, Masaki
WATANABE, Takeshi
AIKAWA, Tatsuo
YUASA, Makoto
EINAGA, Yasuaki
description Electrolytic cells for electrochemical oxygen demand (ECOD) measurements based on total electrolytic decomposition at a boron-doped diamond (BDD) electrode were developed for rapid measurement of organic pollutants at low concentrations. Using improved electrolytic cells designed for efficient mass transfer, the ECOD for 10 μM potassium hydrogen phthalate (theoretical ECOD: 2.3 mg-O2 L–1) was determined in a relatively short electrolysis time. Thus, ECOD measurements using these cells would be useful for estimating organic water pollution in industrial waste and lake water.
doi_str_mv 10.2116/analsci.32.1381
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subjects Advancements in Instrumentation
Analytical Chemistry
Boron-doped diamond electrode
Chemistry
electrochemical oxygen demand
organic water pollution
total electrolysis
title Development of Electrochemical Oxygen Demand Measurement Cells Using a Diamond Electrode
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