Amidinyl Radical Formation through Anodic N−H Bond Cleavage and Its Application in Aromatic C−H Bond Functionalization

We report herein an atom‐economical and sustainable approach to access amidinyl radical intermediates through the anodic cleavage of N−H bonds. The resulting nitrogen‐centered radicals undergo cyclizations with (hetero)arenes, followed by rearomatization, to afford functionalized tetracyclic benzimi...

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Veröffentlicht in:	Angewandte Chemie International Edition 2017-01, Vol.56 (2), p.587-590
Hauptverfasser:	Zhao, Huai‐Bo, Hou, Zhong‐Wei, Liu, Zhan‐Jiang, Zhou, Ze‐Feng, Song, Jinshuai, Xu, Hai‐Chao
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Benzimidazoles Cleavage cyclization electrochemistry Free radicals heterocycles Intermediates Nitrogen radicals Reagents Substrates
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