Manganese Tricarbonyl Complexes with Asymmetric 2‑Iminopyridine Ligands: Toward Decoupling Steric and Electronic Factors in Electrocatalytic CO2 Reduction

Manganese tricarbonyl bromide complexes incorporating IP (2-(phenylimino)­pyridine) derivatives, [MnBr­(CO)3(IP)], are demonstrated as a new group of catalysts for CO2 reduction, which represent the first example of utilization of (phenylimino)­pyridine ligands on manganese centers for this purpose....

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Veröffentlicht in:Inorganic chemistry 2016-12, Vol.55 (24), p.12568-12582
Hauptverfasser: Spall, Steven J. P, Keane, Theo, Tory, Joanne, Cocker, Dean C, Adams, Harry, Fowler, Hannah, Meijer, Anthony J. H. M, Hartl, František, Weinstein, Julia A
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Sprache:eng
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