Significantly Dense Two-Dimensional Hydrogen-Bond Network in a Layered Zirconium Phosphate Leading to High Proton Conductivities in Both Water-Assisted Low-Temperature and Anhydrous Intermediate-Temperature Regions

Significantly Dense Two-Dimensional Hydrogen-Bond Network in a Layered Zirconium Phosphate Leading to High Proton Conductivities in Both Water-Assisted Low-Temperature and Anhydrous Intermediate-Temperature Regions

A highly stable layered zirconium phosphate, (NH4)2[ZrF2(HPO4)2] (ZrP-1), was synthesized by an ionothermal method and contains an extremely dense two-dimensional hydrogen-bond network that is thermally stable up to 573 K, leading to combined ultrahigh water-assisted proton conductivities of 1.45 ×...

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Veröffentlicht in:Inorganic chemistry 2016-12, Vol.55 (24), p.12508-12511
Hauptverfasser: Gui, Daxiang, Zheng, Tao, Xie, Jian, Cai, Yawen, Wang, Yaxing, Chen, Lanhua, Diwu, Juan, Chai, Zhifang, Wang, Shuao
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container_end_page 12511
container_issue 24
container_start_page 12508
container_title Inorganic chemistry
container_volume 55
creator Gui, Daxiang
Zheng, Tao
Xie, Jian
Cai, Yawen
Wang, Yaxing
Chen, Lanhua
Diwu, Juan
Chai, Zhifang
Wang, Shuao
description A highly stable layered zirconium phosphate, (NH4)2[ZrF2(HPO4)2] (ZrP-1), was synthesized by an ionothermal method and contains an extremely dense two-dimensional hydrogen-bond network that is thermally stable up to 573 K, leading to combined ultrahigh water-assisted proton conductivities of 1.45 × 10–2 S cm–1 at 363 K/95% relative humidity and sustainable anhydrous proton conductivity of 1.1 × 10–5 S cm–1 at 503 K.
doi_str_mv 10.1021/acs.inorgchem.6b02308
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title Significantly Dense Two-Dimensional Hydrogen-Bond Network in a Layered Zirconium Phosphate Leading to High Proton Conductivities in Both Water-Assisted Low-Temperature and Anhydrous Intermediate-Temperature Regions
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